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CAS No.: | 7340-90-1 |
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Name: | 5-TERT-BUTYL-2-METHYLTHIOPHENOL |
Article Data: | 1 |
Molecular Structure: | |
Formula: | C11H15S- |
Molecular Weight: | 180.314 |
Synonyms: | 5-tert-butyl-2-methylbenzenethiol; |
Density: | 0.974g/cm3 |
Melting Point: | -10oC |
Boiling Point: | 248.2°Cat760mmHg |
Flash Point: | 95.8°C |
Risk Codes: | R36/38; R51/53 |
Safety: | 7473482 |
PSA: | 38.80000 |
LogP: | 3.58120 |
1,2-bis(5-(tert-butyl)-2-methylphenyl)disulfane
2-methyl-5-tert-butylthiophenol
Conditions | Yield |
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With sodium tetrahydroborate |
1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-D-glucopyranose
2-methyl-5-tert-butylthiophenol
(2-methyl-5-tert-butylphenyl) 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-1-thio-α-D-glucopyranoside
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane | 98% |
1,2,3,5,6-penta-O-benzoyl-D-galactofuranose
2-methyl-5-tert-butylthiophenol
(2-methyl-5-tert-butylphenyl) 2,3,5,6-tetra-O-benzoyl-1-thio-β-D-galactofuranoside
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; for 1.5h; Inert atmosphere; | 97% |
Conditions | Yield |
---|---|
With bis(η3-allyl-μ-chloropalladium(II)); 1,1',3,3'-tetrakis(diphenylphosphino)ferrocene; sodium t-butanolate In toluene for 17h; Catalytic behavior; Inert atmosphere; Schlenk technique; Heating; | 95% |
2-methyl-5-tert-butylthiophenol
β-D-glucose pentaacetate
(2-methyl-5-tert-butylphenyl) 2,3,4,6-tetra-O-acetyl-1-S-β-D-thioglucopyranoside
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane Inert atmosphere; | 94% |
With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; for 16h; Inert atmosphere; | 92% |
With boron trifluoride diethyl etherate In dichloromethane | 85% |
2-methyl-5-tert-butylthiophenol
((2R,3S,4S,5R,6S)-6-(((1S,2S,3R,4S,6R)-4,6-bis((tert-butoxycarbonyl)amino)-3-(((2R,3R,5S,6R)-3-((tert-butoxycarbonyl)methyl)-5-hydroxytetrahydro-2Hpyran-2-yl)oxy)-2-hydroxycyclohexyl)oxy)-4-((tert-butoxycarbonyl)amino)-3,5-dihydroxytetrahydro-2H-pyran-2-yl)methyl 2,4,6-triisopropylbenzenesulfonate
C54H91N5O18S
Conditions | Yield |
---|---|
With caesium carbonate In N,N-dimethyl-formamide at 20℃; | 94% |
1,3,4,6-tetra-O-acetyl-2-(trifluoroacetamido)-2-deoxy-β-D-glucopyranoside
2-methyl-5-tert-butylthiophenol
5-tert-butyl-2-methylphenyl 3,4,6-tri-O-acetyl-2-(trifluoroacetamido)-2-deoxy-1-thio-β-D-glucopyranoside
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; Inert atmosphere; | 93% |
2-methyl-5-tert-butylthiophenol
per-O-acetyl-α-D-mannopyranose
(2-methyl-5-tert-butylphenyl) 2,3,4,6-tetra-O-acetyl-1-thia-α-D-mannopyranoside
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane at -78 - 20℃; Inert atmosphere; | 93% |
Conditions | Yield |
---|---|
Stage #1: 2-methyl-5-tert-butylthiophenol; β-D-galactose peracetate With boron trifluoride diethyl etherate In dichloromethane at 0 - 20℃; for 1h; Stage #2: With sodium methylate In methanol for 0.5h; | 93% |
1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose
2-methyl-5-tert-butylthiophenol
(2-methyl-5-tert-butylphenyl) 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-1-thio-α-D-glucopyranoside
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 8h; Inert atmosphere; | 92% |