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CAS No.: | 7795-91-7 |
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Name: | Ethylene glycol mono-sec-butyl ether |
Molecular Structure: | |
Formula: | C6H14O2 |
Molecular Weight: | 118.176 |
Synonyms: | 2-butan-2-yloxyethanol;2-sec-Butoxyethanol;2-(1-Methylpropoxy)ethanol;Ethanol, 2-sec-butoxy-;Ethanol, 2-sec-butoxy- (6CI,7CI,8CI);2-(1-Methylpropoxy)ethanol;2-sec-Butoxyethanol;Ethylene glycol mono-sec-butyl ether; |
Density: | 0.896g/cm3 |
Melting Point: | -69.47°C (estimate) |
Boiling Point: | 157.8°Cat760mmHg |
Flash Point: | 50.2°C |
Safety: | Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS. |
PSA: | 29.46000 |
LogP: | 0.79380 |
Conditions | Yield |
---|---|
With hydro silicate at 99 - 104℃; |
Conditions | Yield |
---|---|
With diisobutylaluminium hydride; benzene Behandeln einer Loesung des erhaltenen Diisobutylaluminium-<2-sec-butoxy-aethylats> in Aether mit wss.Schwefelsaeure; | |
With lithium aluminium tetrahydride; zirconium(IV) chloride In diethyl ether at 30℃; for 12h; | 86 % Spectr. |
Conditions | Yield |
---|---|
With sulfuric acid at 95℃; |
Conditions | Yield |
---|---|
In benzene |
Conditions | Yield |
---|---|
(i) EtMgBr, (ii) /BRN= 102520/; Multistep reaction; |
Conditions | Yield |
---|---|
In benzene at 80℃; |
2-methyl-1,3-dioxolane
triethylaluminum
A
2-ethoxy-ethanol
B
2-(1-Methylpropoxy)ethanol
Conditions | Yield |
---|---|
With diethylaluminium hydride In hexane; kerosene for 50h; Heating; | A 0.01 mol B 0.03 mol |
2-ethyl-2-methyl-1,3-dioxolane
triethylaluminum
A
2-(1-Methylpropoxy)ethanol
B
2-(1-ethyl-1-methyl-propoxy)-ethanol
Conditions | Yield |
---|---|
With diethylaluminium hydride In hexane; kerosene for 40h; Heating; | A 0.01 mol B 0.03 mol |
2-ethyl-2-methyl-1,3-dioxolane
A
2-(1-Methylpropoxy)ethanol
B
2-(1-ethyl-1-methyl-propoxy)-ethanol
Conditions | Yield |
---|---|
With triethylaluminum; diethylaluminium hydride In hexane; kerosene for 20h; Heating; | A 0.015 mol B 0.015 mol |
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