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CAS No.: | 861892-40-2 |
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Name: | (4R)-1-METHYL-4-(1-METHYLETHENYL)-2-CYCLOHEXEN-1-OL |
Article Data: | 9 |
Molecular Structure: | |
Formula: | C10H16 O |
Molecular Weight: | 152.236 |
Synonyms: | (4R)-1-Methyl-4-isopropenylcyclohex-2-en-1-ol |
Density: | 0.947±0.06 g/cm3(Predicted) |
Boiling Point: | 216.9±40.0 °C(Predicted) |
PSA: | 20.23000 |
LogP: | 2.27970 |
(4R)-limonene 1,2-epoxide
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
Conditions | Yield |
---|---|
Stage #1: (4R)-limonene 1,2-epoxide With sodium tetrahydroborate; diphenyl diselenide In ethanol for 2h; Heating; Stage #2: With dihydrogen peroxide In tetrahydrofuran for 2h; Heating; | 52% |
Stage #1: (4R)-limonene 1,2-epoxide With sodium tetrahydroborate; ethanol; diphenyl diselenide at 0℃; Reflux; Inert atmosphere; Stage #2: With dihydrogen peroxide In tetrahydrofuran; water at 0℃; Reflux; | 52% |
Stage #1: (4R)-limonene 1,2-epoxide With sodium tetrahydroborate; diphenyl diselenide at 0℃; Stage #2: With dihydrogen peroxide at 0℃; Further stages.; | 28% |
D-limonene
A
(2S,4S)-carveol
B
(+)-trans-carveol
C
(R)-Perillyl alcohol
D
(5S)-2-methylene-5-(prop-1-en-2-yl)cyclohexanol
E
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
Conditions | Yield |
---|---|
Stage #1: D-limonene With C48H42N2O4S5 In acetonitrile for 0.5h; Irradiation; Stage #2: With sodium tetrahydroborate In ethanol at 0℃; Darkness; Stage #3: With water In ethanol |
D-limonene
A
5-Isopropenyl-2-methyl-cyclohex-2-enol
B
(5R)-2-methylene-5-(1-methylethenyl)-1-cyclohexanol
C
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
Conditions | Yield |
---|---|
Stage #1: D-limonene With sodium molybdate dihydrate; dihydrogen peroxide; sodium hydroxide In methanol; water for 0.583333h; pH=10; Heating; Stage #2: With sodium sulfite In methanol; water at 60℃; for 3h; Reagent/catalyst; |
carbon dioxide
cis-(R)-limonene oxide
A
L-carveol
B
(R)-dihydrocarvone
C
1-methyl-4-(1-methylethenyl)-1,2-cyclohexanediol
D
(5R)-2-methylene-5-(1-methylethenyl)-1-cyclohexanol
F
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; 3C25H54N(1+)*O24PW4(3-) In neat (no solvent) at 140℃; for 24h; Reagent/catalyst; High pressure; Autoclave; |
carbon dioxide
(1S,2R,4R)-limonene-1,2-epoxide
A
L-carveol
B
1-methyl-4-(1-methylethenyl)-1,2-cyclohexanediol
C
(5R)-2-methylene-5-(1-methylethenyl)-1-cyclohexanol
E
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; 3C25H54N(1+)*O24PW4(3-) In neat (no solvent) at 140℃; for 24h; Reagent/catalyst; High pressure; Autoclave; |
2-(3,5-dihydroxyphenyl)-2-methylhexane
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
(6aR,10aR)-6,6,9-trimethyl-3-(2-methylhexan-2-yl)-6a,7,10,10a-tetrahydro-6H-benzo[c]chromen-1-ol
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene at 20 - 80℃; for 7h; Dean-Stark; | 85.5% |
With toluene-4-sulfonic acid In benzene for 12h; Reflux; |
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
5-(1-hexylcyclopentyl)resorcinol
5-(1-Hexyl-cyclopentyl)-2-((1R,6R)-6-isopropenyl-3-methyl-cyclohex-2-enyl)-benzene-1,3-diol
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In benzene at 10 - 20℃; for 1h; | 85% |
5-(1-adamantanyl)resorcinol
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In chloroform at 65℃; for 6h; | 84% |
methyl 2,4-dihydroxy-6-pentylbenzoate
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
methyl (1'R,2'R)-2,6-dihydroxy-5'-methyl-4-pentyl-2'-(prop-1 -en-2- yl)-1',2',3',4'-tetrahydro-[1,1'-biphenyl]-3-carboxylate
Conditions | Yield |
---|---|
Stage #1: methyl 2,6-dihydroxy-6-pentylbenzoate; (4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol With boron trifluoride diethyl etherate In chlorobenzene at 22℃; Stage #2: With sodium hydrogencarbonate In chlorobenzene at 20℃; for 0.333333h; | 70% |
With boron trifluoride diethyl etherate In chlorobenzene at 20℃; for 1h; Reagent/catalyst; Temperature; Solvent; | 70% |
Stage #1: methyl 2,6-dihydroxy-6-pentylbenzoate; (4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol With boron trifluoride diethyl etherate In chlorobenzene at 22℃; Flow reactor; Stage #2: With sodium hydrogencarbonate In chlorobenzene at 22℃; for 0.333333h; | |
With boron trifluoride diethyl etherate In chlorobenzene at 20℃; for 1h; Solvent; |
5-(8-bromo-2-methyloctan-2-yl)benzene-1,3-diol
(4R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In benzene for 4h; Reflux; | 65% |