100393-43-9

Basic information

• Product Name: α-phenyl-α-(2-pyridyl-N-oxide)ethanol
• Synonyms: α-phenyl-α-(2-pyridyl-N-oxide)ethanol
• CAS NO: 100393-43-9
• Molecular Weight: 215.252
• Mol File: 100393-43-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: α-phenyl-α-(2-pyridyl-N-oxide)ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: α-phenyl-α-(2-pyridyl-N-oxide)ethanol(100393-43-9)
• EPA Substance Registry System: α-phenyl-α-(2-pyridyl-N-oxide)ethanol(100393-43-9)

Safety Data

• Hazardous Substances Data: 100393-43-9(Hazardous Substances Data)

Usage

General Description

α-phenyl-α-(2-pyridyl-N-oxide)ethanol is a chemical compound with the molecular formula C13H13NO2. It is commonly used as a ligand in the synthesis of coordination compounds and metal complexes. α-phenyl-α-(2-pyridyl-N-oxide)ethanol contains a pyridine N-oxide moiety, which imparts unique reactivity and coordination properties. Additionally, the phenyl and hydroxyl groups contribute to its chemical versatility and potential for various applications in organic and inorganic chemistry. α-phenyl-α-(2-pyridyl-N-oxide)ethanol has been studied for its potential as a chelating agent and in catalytic reactions, making it an important compound in the field of chemical synthesis and coordination chemistry.

Upstream product

• 694-59-7 pyridine N-oxide 
• 98-86-2 acetophenone 
• 19490-92-7 1-phenyl-1-(pyridin-2-yl)ethanol 
• 1122-62-9 2-acetylpyridine 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 1217437-09-6 α-(2-pyridyl-N-oxide)styrene 

Relevant articles and documents

-

-

Synthesis and crystal structures of α-phenyl- and α-trifluoromethyl-α-(2-pyridyl-N-oxide)ethanols and α-phenyl-α-(2-pyridyl-N-oxide)ethylene

The X-ray structures of two α-substituted α-(2-pyridyl-N-oxide) ethanols, the α-phenyl- (3a) and α-trifluoromethyl- (3b) derivatives, were determined. On dehydration of 3a, compound 4a was obtained. This study brought a clear proof that the α-(2-pyridyl-N-oxide)ethanols are formed following oxidation with peroxides of their corresponding pyridines. A different molecular packing was observed for the α-trifluoromethyl derivative due to an additional hydrogen bonding. Compound 3a crystallized in the monoclinic space group P 21/n with unit cell parameters a = 5.7416(1) A, b = 14.3841(4) A, c = 13.2821(3) A, β = 94.918(2)°, V = 1092.90(4) A3, Z = 4, D = 1.308 Mg/m 3. Compound 3b crystallized in the triclinic space group P -1 with unit cell parameters a = 6.1209(2) A, b = 8.1938(4) A, c = 9.4675(4) A, α = 73.363(3)°, β = 73.166(3)°, γ = 71.659(3)°, V = 421.32(3) A3, Z = 2, D = 1.633 Mg/m 3. Compound 4a crystallized in the monoclinic space group P 2 1/n with unit cell parameters a = 9.3579(3) A, b = 12.7340(3) A, c = 9.8579(3) A, β = 117.3249(15)°, V = 1043.63(5) A3, Z = 4, D = 1.255 Mg/m3.