100572-83-6Relevant articles and documents
4-alkenyl-1-methoxy-1,4-cyclohexadienes by tandem addition-multistep reduction of alkenyl aldehydes and ketones. Synthesis of 4-alkenyl-3-cyclohexen-1-ones by subsequent hydrolysis
Flisak, Joseph R.,Hall, Stan S.
, p. 7299 - 7305 (2007/10/02)
A series of 4-alkenyl-1-methoxy-1,4-cyclohexadienes were prepared by a tandem addition-multistep reduction procedure. This one-pot process included the addition of 4-methoxyphenyllithium to alkenyl aldehydes and ketones, followed by multistep reduction of
Efficient Syntheses of β-Sesquiphellandrene and Zingiberenol Employing a Tandem Arylation-Multistep Reduction-Hydrolysis Sequence
Flisak, Joseph R.,Hall, Stan S.
, p. 1217 - 1228 (2007/10/02)
The title sesquiterpenes are synthesized in one step from the common intermediate 4-(6-methyl-5-hepten-2-yl)-2-cyclohexen-1-one, which is prepared using a one-pot tandem arylation-multistep reduction-hydrolysis sequence.
Intramolecular Photoaddition of a 1,7-Diene
Croft, Kevin D.,Ghisalberti, Emilio L.,Jefferies, Phillip R.,Stuart, Alan D.,Raston, Colin L.,White, Allan H.
, p. 1473 - 1480 (2007/10/02)
Intramolecular photoaddition of the 1,7-diene system in 4-(1,5-dimethylhex-4-enyl)cyclohex-2-enone (3) yielded, inter alia, two ketones containing the tricyclo5,11>undecan-8-one system.The structure and stereochemistry of these ketones has been determined from X-ray crystallographic analyses of suitable derivatives.