451-55-8

Basic information

• Product Name: 1,3-Cyclohexadiene, 1-(1,5-dimethyl-4-hexenyl)-4-methyl-
• CAS NO: 451-55-8
• Molecular Formula: C15H24
• Molecular Weight: 204.356
• Mol File: 451-55-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3-Cyclohexadiene, 1-(1,5-dimethyl-4-hexenyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Cyclohexadiene, 1-(1,5-dimethyl-4-hexenyl)-4-methyl-(451-55-8)
• EPA Substance Registry System: 1,3-Cyclohexadiene, 1-(1,5-dimethyl-4-hexenyl)-4-methyl-(451-55-8)

Safety Data

• Hazardous Substances Data: 451-55-8(Hazardous Substances Data)

Usage

Molecular structure

A cyclic hydrocarbon with two double bonds, one connected to a methyl group and the other to a 1,5-dimethyl-4-hexenyl group.

Type of compound

Chemical intermediate.

Usage

Commonly used in the production of various other chemicals and products.

Applications

Potential applications in organic synthesis and other chemical processes due to its unique structure and reactivity.

Safety precautions

Must be handled with care and in accordance with safety regulations due to potential hazards and risks associated with its use and handling.

Upstream product

• 372-97-4 farnesyl pyrophosphate 
• 94450-86-9 3-(1,5-Dimethyl-4-hexenyl)-6-methyl-2-cyclohexen-1-on 
• 100572-83-6 4-(1,5-dimethyl-4-hexenyl)-3-cyclohexen-1-one 
• 72055-87-9 rac-3-(6-methylhept-5-en-2-yl)cyclohex-2-en-1-one 
• 85-44-9 phthalic anhydride 
• 100572-87-0 3-(1,5-Dimethyl-4-hexenyl)-6-methyl-2-cyclohexen-1-ol 
• 139623-49-7 4-(1,5-Dimethyl-4-hexenyl)-1-methyl-3-cyclohexen-1-ol 

Relevant articles and documents

Isotope sensitive branching and kinetic isotope effects to analyse multiproduct terpenoid synthases from Zea mays

Multiproduct terpene synthases TPS4-B73 and TPS5-Delprim from Zea mays exhibit isotopically sensitive branching in the formation of mono- and sesquiterpene volatiles. The impact of the kinetic isotope effects and the stabilization of the reactive intermediates by hyperconjugation along with the shift of products from alkenes to alcohols are discussed.

Terpenes and Terpene Derivatives, XVIII. - Concerning the Preparation of rac-γ-Curcumene

Preparation of pure γ-curcumene (3) described by Birch in 1949 via dehydratization of the alcohol 5 with SOCl2/pyridine was not reproducible.Mixtures of α-, β-, and γ-curcumene (1-3) were obtained even with POCl3/pyridine or Burgess reagent.Analogously the secondary alcohol 20 yielded mixtures of 3 and the 1,3-dienes 21 and (presumably) 22. - Li/NH3 reduction of the tert. benzyl alcohol 8 afforded after work-up directly the dienone 15 which with MeLi gave the dehydro derivative 16 of zingiberenol (17).