100701-86-8Relevant articles and documents
Diastereodivergent Control in the Reactions of Allylic and Allenic Organometallic Reagents with Pyruvates
Yamamoto, Yoshinori,Maruyama, Kazuhiro,Komatsu, Toshiaki,Ito, Wataru
, p. 886 - 891 (2007/10/02)
The reaction of crotyl-9-BBN (4a) with pyruvates (3) produced the threo (anti) isomer 5 either predominantly or exclusively.On the other hand, the reaction of allenic organometallic reagents 18 (M = B or Ti) gave the erythro (syn) isomer 20 preferentially