100716-73-2

Basic information

• Product Name: Benzene, 1-chloro-4-[(2-phenylethyl)sulfonyl]-
• CAS NO: 100716-73-2
• Molecular Formula: C14H13ClO2S
• Molecular Weight: 280.775
• Mol File: 100716-73-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-[(2-phenylethyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-[(2-phenylethyl)sulfonyl]-(100716-73-2)
• EPA Substance Registry System: Benzene, 1-chloro-4-[(2-phenylethyl)sulfonyl]-(100716-73-2)

Safety Data

• Hazardous Substances Data: 100716-73-2(Hazardous Substances Data)

Upstream product

• 14752-66-0 sodium p-chlorobenzenesulphinate 
• 103-63-9 1-phenyl-2-bromoethane 
• 31599-09-4 (E)-(1-chloro-4-(2-chloro-2-phenylethene)sulfonyl)benzene 
• 31599-09-4 (Z)-1-chloro-2-(4-chlorophenylsulphonyl)-1-phenylethene 
• 100-39-0 benzyl bromide 
• 98-57-7 4-chlorophenyl methyl sulfone 
• 70998-28-6 p-chlorophenyl 2-phenylethyl sulfide 
• 933-01-7 4-chloro-benzenesulfenyl chloride 
• 536-74-3 phenylacetylene 
• 86602-25-7 (Z)-1-chloro-2-(4-chlorophenylthio)-1-phenylethene 
• 86602-23-5 (E)-(2-chloro-1-phenylvinyl)(4-chlorophenyl)sulfane 

Downstream Products

• 100-42-5 styrene 
• 869579-46-4 1-Chloro-4-(1-phenyl-pent-4-ene-2-sulfonyl)-benzene 
• 3909-96-4 (1E,3E)-1-phenyl-1,3-pentadiene 
• 55666-17-6 (1E)-1,4-pentadienylbenzene 
• 91166-39-1 (E)-penta-2,4-dien-1-ylbenzene 
• 558462-40-1 4-[1-Benzyl-5-(methylsulfonyl)pentylsulfonyl]-1-chlorobenzene 

Relevant articles and documents

Alkene synthesis: Elimination of arenesulfinic acid from alkyl aryl sulfones using potassium trimethylsilanolate as base

The use of potassium trimethylsilanolate as base to induce elimination of potassium arenesulfinate from alkyl aryl sulfones to produce E-alkenes is described. The reaction was appropriate for substrates containing a benzyl or allyl group α to the sulfone

Addition of 4-Chlorobenzenesulphenyl Chloride to 3-Methylbut-1-yne, Hex-1-yne, and Phenylacetylene: Isomerisation and Hydrolysis of the Adducts

The addition of (4-ClC6H4SCl, (2), to RCH(*)CH, (1; R=Pri, Bun), gives (E)-4-ClC6H4(R)C(*)C(H)Cl, (E)-(3), and (E)-4-ClC6H4(H)C(*)C(R)Cl, (E)-(4) in a fixed ratio; the addition to (1; R=Ph) gives regiospecifically (E)-(3; R=Ph) in ethyl acetate, but different proportions of (E)-(3) and (E)-(4) (R=Ph), in chloroform, sym-tetrachloroethane, and acetic acid.With an excess of the sulphenyl chloride (2), (E)-(3) and (E)-(4) isomerize to (Z)-(4) (same R).The sulphuric-acid catalysed hydrolysis of (E)-(3; R=Pri, Bun, Ph) gives α-chloroketones RCOCH2Cl(5) (same R).The (E)-(4) isomers do not hydrolyse.