100956-53-4

Basic information

• Product Name: (Z)-cyclooct-2-en-1-yl 4-nitrobenzoate
• Synonyms: (Z)-cyclooct-2-en-1-yl 4-nitrobenzoate
• CAS NO: 100956-53-4
• Molecular Weight: 275.304
• Mol File: 100956-53-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-cyclooct-2-en-1-yl 4-nitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-cyclooct-2-en-1-yl 4-nitrobenzoate(100956-53-4)
• EPA Substance Registry System: (Z)-cyclooct-2-en-1-yl 4-nitrobenzoate(100956-53-4)

Safety Data

• Hazardous Substances Data: 100956-53-4(Hazardous Substances Data)

Upstream product

• 931-88-4 1,2-cyclooctene 
• 62-23-7 4-nitro-benzoic acid 
• 122-04-3 4-nitro-benzoyl chloride 
• 931-88-4 cis-Cyclooctene 
• 16166-61-3 tert-butyl 4-nitrobenzoperoxoate 

Relevant articles and documents

Effects of Silver Carbonate and p-Nitrobenzoic Acid for Accelerating Palladium-Catalyzed Allylic C-H Acyloxylation

An allylic C-H acyloxylation of terminal alkenes with 4-nitrobenzoic acid was assisted by a bidentate-sulfoxide-ligated palladium catalyst combined with 1,4-benzoquinone and Ag2CO3 under mild reaction conditions. The catalytic activity was remarkably enhanced by Ag2CO3 as an additive and 4-nitrobenzoic acid as a carboxylate source; both components were essential to exhibiting high catalytic activity, high branch selectivity, and a wide substrate scope with low loading of the palladium catalyst. Branch-selective allylic acyloxylation of ethyl 7-octenoate (1a) gave the product which was led to ethyl 6,8-dihydroxyoctanoate (5), a useful synthetic intermediate of (R)-α-lipoic acid.