101468-97-7

Basic information

• Product Name: DL-Phenylalanine, N-benzoyl-4-nitro-
• CAS NO: 101468-97-7
• Molecular Formula: C16H14N2O5
• Molecular Weight: 314.298
• Mol File: 101468-97-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: DL-Phenylalanine, N-benzoyl-4-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: DL-Phenylalanine, N-benzoyl-4-nitro-(101468-97-7)
• EPA Substance Registry System: DL-Phenylalanine, N-benzoyl-4-nitro-(101468-97-7)

Safety Data

• Hazardous Substances Data: 101468-97-7(Hazardous Substances Data)

Upstream product

• 7152-75-2 (Z)-2-phenyl-4-(4-nitrobenzylidene)-(4H)-1,3-oxazol-5-one 
• 669775-21-7 methyl (N-benzoyl)-4'-nitrophenylalaninate 
• 1991-83-9 4-nitrophenylalanine 
• 98-88-4 benzoyl chloride 

Downstream Products

• 76684-77-0 N-Benzoyl-p-amino-D-phenylalanine 
• 69935-12-2 (S)-4-nitro-N-benzoyl-phenylalanine 
• 106943-05-9 N-[1-(4-Amino-benzyl)-3,3,3-trifluoro-2-oxo-propyl]-benzamide; hydrochloride 
• 106942-39-6 4-(4-Nitro-benzyl)-2-phenyl-4-(2,2,2-trifluoro-acetyl)-4H-oxazol-5-one 
• 106746-00-3 N-[3,3,3-Trifluoro-2-oxo-(4-nitrophenylmethyl)propyl]benzamide 
• 1991-83-9 4-nitrophenylalanine 
• 106942-32-9 2-phenyl-4-<(4-nitro)phenylmethyl>-5(4H)-oxazolone 
• 877036-05-0 4-amino-N-benzoyl-DL-phenylalanine 
• 949-99-5 4-nitro-3-phenyl-L-alanine 
• 76684-78-1 N-Benzoyl-p-nitro-D-phenylalanine 

Relevant articles and documents

Solid phase reduction of oxazolones using BER-Ni2B-A simple synthesis of N-benzoylphenylalanines

Borohydride exchange resin (BER)-Ni2B is successfully used as a reagent for the solid phase reduction of the C-4 exocyclic double bond of oxazolones to give the N-benzoylphenylalanines and hence the corresponding amino acids.

SYNTHESIS OF FLUORINATED α-AMINO KETONES PART I: α-BENZAMIDOALKYL MONO- DI- AND TRIFLUOROMETHYL KETONES

2-Phenyl-5(4H)-oxazolones, obtained from α-amino acids, are reacted with di- and trifluoro acetic anhydride by a modified Dakin-West procedure to yield in a one-pot reaction α-benzamidoalkyl-di- and trifluoromethyl ketones in good yields.The monofluoromethyl analogues were also prepared from α-amino acids, however the use of the highly toxic fluoroacetic anhydride was avoided.The key step is the halogen exchange reaction on the corresponding bromomethyl ketone.