1021154-59-5Relevant articles and documents
Synthesis of indoles via electron-catalyzed intramolecular C?N bond formation
Bugaenko, Dmitry I.,Dubrovina, Anastasia A.,Yurovskaya, Marina A.,Karchava, Alexander V.
supporting information, p. 7358 - 7362 (2018/12/13)
A new protocol for the preparation of N-substituted indole-3-carboxylates has been developed. The key C?N bond formation occurs under transition-metal-free conditions employing a t-BuOK/DMF system without special initiators or additives. Across a number o
N-cyclopropylation of indoles and cyclic amides with copper(II) reagent
Tsuritani, Takayuki,Strotman, Neil A.,Yamamoto, Yuhei,Kawasaki, Masashi,Yasuda, Nobuyoshi,Mase, Toshiaki
supporting information; experimental part, p. 1653 - 1655 (2009/04/07)
Copper-mediated coupling reactions of cyclopropylboronic acid with indoles and cyclic amides are described. The process utilizes catalytic or stoichiometric amounts of copper(ll) acetate, DMAP, and NaHMDS at 95 °C under an atmosphere containing oxygen. A variety of functional groups remain intact throughout the reaction.
