102130-00-7Relevant articles and documents
A Convenient Chemoenzymatic Synthesis of (R)- and (S)-(Chloromethyl)oxirane
Chen, Ching-Shih,Liu, Yeuk-Chuen,Marsella, Michael
, p. 2559 - 2561 (2007/10/02)
(R)- and (S)-1-Chloro-3-tosyloxypropan-2-ol have been prepared by biocatalysed enantioselective esterification in hexane, and in turn could be readily converted into optically active (chloromethyl)oxirane in high yield.
Lipase-catalyzed Stereoselective Hydrolysis of 2-Acyloxy-3-chloropropyl p-toluenesulfonate
Hamaguchi, Shigeki,Ohashi, Takehisa,Watanabe, Kiyoshi
, p. 375 - 380 (2007/10/02)
Lipase-catalyzed stereoselective hydrolysis of 2-acyloxy-3-chloropropyl p-toluenesulfonate (1) was investigated.From the screening tests, lipases from Pseudomonas aeruginosa, Aspergillus niger, Mucor species, Rhizopus delemar and Rhizopus japonicus were f