102606-95-1

Basic information

• Product Name: Benzenemethanol, 3-fluoro-, acetate
• Synonyms: 3-flourobenzyl acetate
• CAS NO: 102606-95-1
• Molecular Formula: C9H9FO2
• Molecular Weight: 168.168
• Mol File: 102606-95-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 200.8±15.0 °C(Predicted)
• Density: 1.148±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzenemethanol, 3-fluoro-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 3-fluoro-, acetate(102606-95-1)
• EPA Substance Registry System: Benzenemethanol, 3-fluoro-, acetate(102606-95-1)

Safety Data

• Hazardous Substances Data: 102606-95-1(Hazardous Substances Data)

Usage

Chemical compound

Benzenemethanol, 3-fluoro-, acetate

Also known as

3-Fluorobenzyl alcohol acetate

Physical state

Colorless, flammable liquid

Common uses

Intermediate in pharmaceutical and agrochemical synthesis, solvent, organic synthesis

Applications

Industrial and research purposes

Safety considerations

Flammability and potential health hazards

Upstream product

• 456-47-3 3-fluoro-benzenemethanol 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 

Downstream Products

• 456-47-3 3-fluoro-benzenemethanol 

Relevant articles and documents

Synthesis and characterization of ionic liquid immobilized on magnetic nanoparticles: A recyclable heterogeneous organocatalyst for the acetylation of alcohols

Herein, we describe a simple and efficient procedure for the preparation of 3-((3-(trisilyloxy)propyl)propionamide)-1-methylimidazolium chloride ionic liquid supported on magnetic nanoparticle (TPPA-IL-Fe3O4). The structure of this magnetic ionic liquid is fully characterized by FT-IR, TGA, XRD, VSM, SEM, EDX and DLS techniques. TPPA-IL-Fe3O4 is employed as a catalyst for the acetylation of alcohols with acetic anhydride under mild and heterogeneous conditions at room temperature with good to excellent yields. The magnetic catalyst could be readily separate from the reaction media by simple magnetic decantation, and reused several times without significant loss of its catalytic activity.

SUBSTITUENT EFFECTS IN THE PHOTOSOLVOLYSIS OF BENZYL DERIVATIVES. GENERAL STRUCTURE-REACTIVITY RELATIONSHIPS.

The relative reactivity of photosolvolysis of a number of substituted benzyl acetates is in the order ortho > meta > para, these substitutent effects being apparently additive, as suggested by the relative reactivity of photomethanolysis of several dimethoxy-susbstituted benzyl alcohols.

L-pyrrolidine-2-carboxylic acid-4-hydrogen sulfate (supported on silica gel) as a new and efficient catalyst for acylation of alcohols, phenols and amines under solvent-free conditions

In the present work, L-pyrrolidine-2-carboxylic acid-4-hydrogen sulfate, supported on silica gel was prepared and characterized by Mass spectroscopy, 1H NMR, 13CNMR, FT IR and elemental analysis (CHN) methods. This heterogenized catalyst can be used as an efficient catalyst for the acylation of alcohols, phenols, and amines with acetic anhydride under mild and solvent-free conditions. Simple work-up, stability of the catalyst, nontoxicity and good to high yields are the advantages of this work.