1026466-52-3Relevant articles and documents
Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C-H bonds
Hu, Xile,Zhang, Lei
, p. 10786 - 10791 (2020/10/26)
Convergent paired electrosynthesis is an energy-efficient approach in organic synthesis; however, it is limited by the difficulty to match the innate redox properties of reaction partners. Here we use nickel catalysis to cross-couple the two intermediates
Threefold and chemoselective couplings of triarylbismuths with benzylic chlorides and iodides using palladium catalysis
Rao, Maddali L. N.,Dhanorkar, Ritesh J.
, p. 13134 - 13144 (2014/04/03)
This paper describes the palladium-catalyzed studies on threefold coupling of triarylbismuth reagents with benzylic chlorides and iodides. The optimized protocol conditions are operationally simple, delivering threefold coupling of a variety of triarylbismuths in combination with benzylic chlorides and iodides. The two optimized protocols allowed the synthesis of a diverse range of unsymmetrical diarylmethanes in an efficient manner. As part of this study, chemoselective transformation of benzylic chlorides and iodides was also achieved. This journal is the Partner Organisations 2014.
Pd-catalyzed chemoselective threefold cross-coupling of triarylbismuths with benzylic bromides
Rao, Maddali L. N.,Dhanorkar, Ritesh J.
, p. 6794 - 6798 (2013/05/23)
An efficient palladium-catalyzed protocol was demonstrated for the chemoselective cross-coupling of functionalized benzylic bromides with triarylbismuth reagents. Under the established conditions, catalyzed by palladium in the presence of K3PO
