103185-03-1

Basic information

• Product Name: 2-Propen-1-one, 1-(4-methoxyphenyl)-2-phenyl-
• CAS NO: 103185-03-1
• Molecular Formula: C16H14O2
• Molecular Weight: 238.286
• Mol File: 103185-03-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 1-(4-methoxyphenyl)-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 1-(4-methoxyphenyl)-2-phenyl-(103185-03-1)
• EPA Substance Registry System: 2-Propen-1-one, 1-(4-methoxyphenyl)-2-phenyl-(103185-03-1)

Safety Data

• Hazardous Substances Data: 103185-03-1(Hazardous Substances Data)

Upstream product

• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 103-82-2 phenylacetic acid 
• 95092-10-7 N-methoxy-N-methyl-2-phenylacetamide 
• 5739-38-8 1-(4-methoxyphenyl)-3-phenylpropan-1-one 
• 40327-51-3 1-(p-methoxyphenyl)-3-phenyl-2,3-epoxy-1-propanone 
• 93011-61-1 3-(4-methoxyphenyl)-3-oxo-2-phenylpropanal 
• 959-23-9 4'-methoxychalcone 
• 100-07-2 4-methoxy-benzoyl chloride 
• 3156-07-8 methyl phenyl ketene 
• 50-00-0 formaldehyd 
• 1023-17-2 4-methoxyphenyl benzyl ketone 
• 5422-47-9 1-(4-methoxyphenyl)-2-phenylethan-1-ol 
• 4456-36-4 di(p-methoxyphenyl)tellurium dichloride 
• 201230-82-2 carbon monoxide 

Downstream Products

• 27536-36-3 1-(4-methoxy-phenyl)-2-phenyl-3-piperidin-1-yl-propan-1-one 
• 855613-52-4 (4-methoxy-phenyl)-[6-(4-methoxy-phenyl)-2,5-diphenyl-3,4-dihydro-2H-pyran-2-yl]-ketone 
• 855911-66-9 2-hydroxy-1,6-bis-(4-methoxy-phenyl)-2,5-diphenyl-hexane-1,6-dione 
• 116375-64-5 3-(tert-Butyl-hydroxy-amino)-1-(4-methoxy-phenyl)-2-phenyl-propan-1-one 

Relevant articles and documents

Palladium- and copper-catalyzed cross-coupling and carbonylative cross-coupling of organotellurium compounds with organostannanes

The palladium- and copper-catalyzed cross-coupling of diaryl- or divinyl tellurium dichlorides with organostannanes has been achieved in the presence of PdCl2 (10 mol%) or CuI (10 mol%) with Cs2CO3 (2 equiv.) in MeCN in good to moderate yields; alternatively, the palladium- and copper-catalyzed carbonylative cross-coupling of organotellurium dichlorides with organostannanes was readily accomplished under atmospheric pressure of CO in good to moderate yields.

Asymmetric Catalytic Epoxidation of Terminal Enones for the Synthesis of Triazole Antifungal Agents

An enantioselective epoxidation of α-substituted vinyl ketones was realized to construct the key epoxide intermediates for the synthesis of various triazole antifungal agents. The reaction proceeded efficiently in high yields with good enantioselectivities by employing a chiral N,N′-dioxide/ScIII complex as the chiral catalyst and 35% aq. H2O2 as the oxidant. It enabled the facile transformation for optically active isavuconazole, efinaconazole, and other potential antifungal agents.

A methylene compound of preparation method and its application (by machine translation)

The invention discloses a methylene compound of preparation method and its application, relates to the field of organic synthesis, the process comprises: 1) in the presence of a three-valent metal salt catalyst, will arone compound and halogen methyl radical trialkyl ammonium salt dissolved in a solvent, 2) 80 - 130 °C reaction 1 - 4 hours, separated and purified α - the methyl radical is fragrant compounds, the reaction environment pollution is small, substrate and wide range of application. (by machine translation)