103323-61-1Relevant articles and documents
Persistent radical cation solutions from the reaction between aromatics and bromine, chlorine or iodine chloride in 1,1,1,3,3,3-hexafluoropropan-2-ol at room temperature
Eberson, Lennart,Hartshorn, Michael P.,Radner, Finn,Persson, Ola
, p. 215 - 216 (1996)
The treatment of reactive aromatic compounds by bromine, chlorine or iodine chloride in 1,1,1,3,3,3-hexafluoropropan-2-ol gives persistent solutions of the corresponding radical cations, in spite of the fact that a nucleophile, a chloride or bromide ion,
Regioselective bromination of 1,4-dimethoxy-2,3-dimethylbenzene and conversion into sulfur-functionalised benzoquinones
Aitken, R. Alan,Jethwa, Siddharth J.,Richardson, Neville V.,Slawin, Alexandra M.Z.
supporting information, p. 1563 - 1566 (2018/03/29)
The NBS bromination of 1,4-dimethoxy-2,3-dimethylbenzene has been examined under a variety of conditions in both 1,1,1-trichloroethane and benzotrifluoride. Four different bromination products have been isolated including the previously unknown 1-bromo-4-
Synthesis of murrayaquinone A and analogues via ring-closing C-H arylation
Bedford, Robin B.,Bowen, John G.,Weeks, Amanda L.
, p. 4389 - 4394 (2013/06/26)
A compact synthesis of Murrayaquinone A is reported, based on sequential Buchwald-Hartwig amination/annulative C-H activation followed by oxidation of the intermediate carbazole. The methodology can be readily extended to other analogues with electron-rich quinone rings.
