581807-68-3

Basic information

• Product Name: Benzaldehyde, 2,5-dihydroxy-3,4-dimethyl-
• CAS NO: 581807-68-3
• Molecular Formula: C9H10O3
• Molecular Weight: 166.177
• Mol File: 581807-68-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzaldehyde, 2,5-dihydroxy-3,4-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2,5-dihydroxy-3,4-dimethyl-(581807-68-3)
• EPA Substance Registry System: Benzaldehyde, 2,5-dihydroxy-3,4-dimethyl-(581807-68-3)

Safety Data

• Hazardous Substances Data: 581807-68-3(Hazardous Substances Data)

Upstream product

• 103323-61-1 1-bromo-2,5-dimethoxy-3,4-dimethylbenzene 
• 39021-83-5 3,6-dimethoxy-o-xylene 
• 86489-95-4 2,5-dimethoxy-3,4-dimethylbenzaldehyde 

Downstream Products

• 581807-69-4 2-hydroxy-3,4-dimethyl-5-(tetrahydro-pyran-2-yloxy)-benzaldehyde 
• 855286-83-8 5-bromo-6-hydroxy-7,8-dimethyl-2-oxo-2H-chromene-3-carboxylic acid 
• 854661-82-8 2-bromo-3,6-dihydroxy-4,5-dimethyl-benzaldehyde 

Relevant articles and documents

Total synthesis of (R, R, R)-γ-tocopherol through cu-catalyzed asymmetric 1,2-addition

Based on the asymmetric copper-catalyzed 1,2-addition of Grignard reagents to ketones, (R, R, R)-γ-tocopherol has been synthesized in 36% yield over 12 steps (longest linear sequence). The chiral center in the chroman ring was constructed with 73% ee by the 1,2-addition of a phytol-derived Grignard reagent to an a-bromo enone prepared from 2,3-dimethylquinone.