1034014-59-9

Basic information

• Product Name: 1-(dodec-1-ylsulfanyl)-2-phenylethyne
• Synonyms: 1-(dodec-1-ylsulfanyl)-2-phenylethyne
• CAS NO: 1034014-59-9
• Molecular Weight: 302.524
• Mol File: 1034014-59-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-(dodec-1-ylsulfanyl)-2-phenylethyne(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(dodec-1-ylsulfanyl)-2-phenylethyne(1034014-59-9)
• EPA Substance Registry System: 1-(dodec-1-ylsulfanyl)-2-phenylethyne(1034014-59-9)

Safety Data

• Hazardous Substances Data: 1034014-59-9(Hazardous Substances Data)

Upstream product

• 112-55-0 1-dodecylthiol 
• 70-11-1 α-bromoacetophenone 
• 77270-21-4 2-(dodecylsulfanyl)-1-phenylethanone 
• 934499-56-6 1-[(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfanyl]dodecane 
• 536-74-3 phenylacetylene 
• 2757-37-1 didodecyl disulfide 
• 28519-34-8 S-dodecyl 4-methylbenzenesulfonothioate 

Downstream Products

• 1034014-66-8 (E)-1-dodecylsulfanyl-2-phenylethenyl diphenyldithiophosphinate 
• 88708-53-6 1-(dodec-1-ylsulfanyl)-2-phenylethene 

Relevant articles and documents

Convenient and efficient synthesis of functionalized unsymmetrical alkynyl sulfides

We developed a simple and efficient method for the synthesis of functionalized unsymmetrical alkynyl sulfides under mild conditions in good yields. The designed method is based on the reaction of 5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-disulfanyl derivatives with lithium acetylides. The developed method allows the preparation of unsymmetrical alkynyl sulfides bearing additional hydroxyl, carboxyl, or amino functionalities.

Convenient and Efficient Diastereoselective Preparation of Functionalized Z-Alkenyl Sulfides

We have developed an efficient and convenient regio- and stereoselective reduction of the alkynyl sulfides with pinacolborane in the presence of copper(I) chloride to produce (Z)-alkenyl sulfides in good and very good yields. The functionalized alkynyl sulfides are readily available based on the reaction of lithium acetylides with thiotosylates under mild conditions.