934499-56-6Relevant articles and documents
DDQ-mediated synthesis of functionalized unsymmetrical disulfanes
Musiejuk, Mateusz,Klucznik, Tomasz,Rachon, Janusz,Witt, Dariusz
, p. 31347 - 31351 (2015)
We developed a simple and efficient method for the synthesis of functionalized unsymmetrical disulfanes under mild conditions in good yields. The designed method is based on the reaction of bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfane with thiols in the presence of 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ). The developed method allows the preparation of unsymmetrical disulfanes bearing additional hydroxy, carboxy, or amino functionalities.