1039768-40-5

Basic information

• Product Name: (S)-3-(dimethylphenylsilyl)-3-phenylpropanoic acid 2,2,2-trifluoroethyl ester
• Synonyms: (S)-3-(dimethylphenylsilyl)-3-phenylpropanoic acid 2,2,2-trifluoroethyl ester
• CAS NO: 1039768-40-5
• Molecular Weight: 366.455
• Mol File: 1039768-40-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-3-(dimethylphenylsilyl)-3-phenylpropanoic acid 2,2,2-trifluoroethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-(dimethylphenylsilyl)-3-phenylpropanoic acid 2,2,2-trifluoroethyl ester(1039768-40-5)
• EPA Substance Registry System: (S)-3-(dimethylphenylsilyl)-3-phenylpropanoic acid 2,2,2-trifluoroethyl ester(1039768-40-5)

Safety Data

• Hazardous Substances Data: 1039768-40-5(Hazardous Substances Data)

Upstream product

• 80054-97-3 (E)-3-phenyl-2-propenoic acid 2,2,2-trifluoroethyl ester 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 1039768-24-5 (Z)-3-phenyl-2-propenoic acid 2,2,2-trifluoroethyl ester 

Downstream Products

• 23522-66-9 2,2,2-trifluoroethyl 3-phenylpropanoate 

Relevant articles and documents

Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon

A rhodium(I)-catalyzed activation of a silicon-boron linkage, that is, the transmetalation of silicon from boron to rhodium(I) by means of an RhI-OH complex, enables the conjugate transfer of nucleophilic silicon onto α,β-unsaturated acceptors. Pre- or in situ formed cationic rhodium(I)-binap complexes catalyze this novel carbon-silicon bond formation with exceptional enantiocontrol, 92 to >99% ee for cyclic carbonyl and carboxyl compounds as well as >99% ee for acyclic carboxyl compounds.