10470-07-2

Basic information

• Product Name: Benzene, 1,1'-(1-cyclohexene-1,4-diyl)bis-
• CAS NO: 10470-07-2
• Molecular Formula: C18H18
• Molecular Weight: 234.341
• Mol File: 10470-07-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-cyclohexene-1,4-diyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-cyclohexene-1,4-diyl)bis-(10470-07-2)
• EPA Substance Registry System: Benzene, 1,1'-(1-cyclohexene-1,4-diyl)bis-(10470-07-2)

Safety Data

• Hazardous Substances Data: 10470-07-2(Hazardous Substances Data)

Upstream product

• 4894-75-1 1-phenyl-4-cyclohexanone 
• 100-58-3 phenylmagnesium bromide 
• 591-50-4 iodobenzene 
• 110-83-8 cyclohexene 
• 6249-81-6 3-phenyl-but-3-en-2-ol 
• 190369-93-8 Toluene-4-sulfonic acid 2-phenyl-hex-5-ynyl ester 
• 10468-74-3 1,4-diphenyl-1-cyclohexanol 
• 143-66-8 sodium tetraphenyl borate 
• 130399-91-6 Trifluoro-acetic acid 4-phenyl-cyclohex-1-enyl ester 
• 100-42-5 styrene 
• 2288-18-8 2-phenyl-1,3-butadiene 

Downstream Products

• 108-95-2 phenol 
• 1257544-68-5 6-oxo-3,6-diphenylhexanoic acid 
• 21072-41-3 (Z)-1,4-diphenylcyclohexane 
• 21072-42-4 trans-1,4-diphenylcyclohexane 
• 92-94-4 [1,1';4',1'']terphenyl 

Relevant articles and documents

Selective heck arylation of cyclohexene with homogeneous and heterogeneous palladium catalysts

Palladium catalysts containing Pd(II) supported on Al2O 3 and alumina-based mixed oxides, Al2O3- ZrO2, Al2O3-CeO2, and Al 2O3-Fe2O3, are very effective in the Heck coupling of iodobenzene with cyclohexene in DMF solution. The best results, up to 81% of monoarylated products with a selectivity to 4-phenylcyclohexene (3) close to 90% were obtained with KOH as a base. The catalytic activity of palladium supported on aluminabased oxides was compared with that of homogeneous precursors, such as Pd(OAc)2 and PdCl 2(PhCN)2, used in [Bu4N]Br as the reaction medium. Under such conditions homogeneous systems were more selective and produced up to 60% of monoarylated products with a selectivity to 3 close to 60%. Copyright

Palladium-Catalyzed Cross-Coupling Reactions of Vinyl and Aryl Triflates with Tetraarylborates

Sodium tetraarylborates 2 have been found to couple efficiently with vinyl and aryl triflates 1 in the presence of a palladium(0) catalyst to afford arylalkenes and biaryls 3 in good yields and under mild conditions.