105096-76-2

Basic information

• Product Name: 1-hydroxy-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-9-phenylsulfonyl-2,6,8-nonatriene
• Synonyms: 1-hydroxy-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-9-phenylsulfonyl-2,6,8-nonatriene
• CAS NO: 105096-76-2
• Molecular Weight: 428.636
• Mol File: 105096-76-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-hydroxy-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-9-phenylsulfonyl-2,6,8-nonatriene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-hydroxy-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-9-phenylsulfonyl-2,6,8-nonatriene(105096-76-2)
• EPA Substance Registry System: 1-hydroxy-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-9-phenylsulfonyl-2,6,8-nonatriene(105096-76-2)

Safety Data

• Hazardous Substances Data: 105096-76-2(Hazardous Substances Data)

Upstream product

• 60-29-7 diethyl ether 
• 429-41-4 tetrabutyl ammonium fluoride 
• 103905-09-5 1-acetoxy-6-bromo-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexene-1-yl)-9-phenylsulfonyl-2,7-nonadiene 
• 103905-01-7 1-acetoxy-8-hydroxy-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-9-(phenylsulfonyl)-2(E),6(E)-nonadiene 
• 56691-74-8 {[(2,6,6-trimethyl-1-cyclohexen-1-yl)methyl]sulfonyl}benzene 
• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 37905-03-6 8-hydroxygeranyl acetate 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 103905-08-4 1-acetoxy-6-chloro-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexene-1-yl)-9-phenylsulfonyl-2,7-nonadiene 

Downstream Products

• 127-47-9 Retinol acetate 
• 29584-22-3 9-cis-Vitamin-A-acetat 
• 29443-87-6 11-cis-Vitamin-A-acetat 
• 34356-31-5 (7E,9E,11E,13Z)-retinyl acetate 

Relevant articles and documents

New sulfonyl compound and use of said compound in the process of producing vitamin A or its esters

The invention relates to a new sulfonyl compound having the general formula wherein R1is an unsubstituted or substituted aryl group; and R2is a C1-C20 alkyl group, a C2-C20 alkenyl group or a C2-C20 alkynyl group, which groups may be substituted with one or more substituents selected from the group consisting of C1-C4 alkoxy, halogen, unsubstituted aryl and substituted aryl; or wherein R2 is a tri(hydrocarbyl)silyl group, an optionally lower-alkyl- substituted dihydro- or tetrahydropyran-2-yl group, an optionally lower- alkyl-substitute dihydro- or tetrahydro-fur-2-yl group, or a lower alkoxyalkylgroup. This sulfonyl compound can be used as an intermediate in the process of producing vitamin A or its esters.

Stereocontrolled synthesis of vitamin A through a double elimination reaction. A novel convergent C10 + C10 route

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