105342-80-1

Basic information

• Product Name: Acetic acid (1S,2R,3S,3aR,4aR,8aR,8bS)-8a-acetoxymethyl-3-chloro-6,8b-dimethyl-2-(toluene-4-sulfonyloxy)-3a-(toluene-4-sulfonyloxymethyl)-2,3,3a,4a,7,8,8a,8b-octahydro-1H-benzo[b]cyclopenta[d]furan-1-yl ester
• CAS NO: 105342-80-1
• Molecular Weight: 711.251
• Mol File: 105342-80-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid (1S,2R,3S,3aR,4aR,8aR,8bS)-8a-acetoxymethyl-3-chloro-6,8b-dimethyl-2-(toluene-4-sulfonyloxy)-3a-(toluene-4-sulfonyloxymethyl)-2,3,3a,4a,7,8,8a,8b-octahydro-1H-benzo[b]cyclopenta[d]furan-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (1S,2R,3S,3aR,4aR,8aR,8bS)-8a-acetoxymethyl-3-chloro-6,8b-dimethyl-2-(toluene-4-sulfonyloxy)-3a-(toluene-4-sulfonyloxymethyl)-2,3,3a,4a,7,8,8a,8b-octahydro-1H-benzo[b]cyclopenta[d]furan-1-yl ester(105342-80-1)
• EPA Substance Registry System: Acetic acid (1S,2R,3S,3aR,4aR,8aR,8bS)-8a-acetoxymethyl-3-chloro-6,8b-dimethyl-2-(toluene-4-sulfonyloxy)-3a-(toluene-4-sulfonyloxymethyl)-2,3,3a,4a,7,8,8a,8b-octahydro-1H-benzo[b]cyclopenta[d]furan-1-yl ester(105342-80-1)

Safety Data

• Hazardous Substances Data: 105342-80-1(Hazardous Substances Data)

Upstream product

• 2270-40-8 4,15-diacetoxyscirpenol 
• 6121-61-5 4β,15-diacetoxy-2β-chloroapotrichothec-9-ene-3α,13-diol 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant articles and documents

Phytotoxic Compound Produced by Fusarium equiseti. Part 8. Acid Catalysed Rearrangement of 12,13-Epoxytrichothec-9-enes

The acid catalysed rearrangement of 12,13-epoxytrichothec-9-enes to give biologically inactive 10,13-cyclotrichothecane or apotrichothec-9-ene products depends on the substitution pattern of both rings A and C.The former rearrangement is adversely affected by 8α-substitution and by the presence of a 4,15-macrolide ring; the latter rearrangement by 7α- and by 3α-substitution.Compared with the trichothecene, the greater flexibility of the apotrichothecene skeleton is reflected in the range of values for the ring C vicinal coupling constants in the 1H n.m.r. spectra.