105473-15-2Relevant articles and documents
Reaction of (α-Thioalkyl)chromium Compounds Prepared by Chromium(II) Reduction of α-Halo Sulfides
Nakatsukasa, Shigeki,Takai, Kazuhiko,Utimoto, Kiitiro
, p. 5045 - 5046 (2007/10/02)
Reduction of α-chloroalkyl phenyl (or methyl) sulfides with chromium(II) chloride in THF proceeds smoothly in the presence of LiI.The resulting (α-thioalkyl)chromium reagents add to aldehydes in a chemo- and stereoselective manner.