106119-12-4

Basic information

• Product Name: Morpholine, 4-[(4-chlorophenyl)thio]-
• CAS NO: 106119-12-4
• Molecular Formula: C10H12ClNOS
• Molecular Weight: 229.73
• Mol File: 106119-12-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Morpholine, 4-[(4-chlorophenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Morpholine, 4-[(4-chlorophenyl)thio]-(106119-12-4)
• EPA Substance Registry System: Morpholine, 4-[(4-chlorophenyl)thio]-(106119-12-4)

Safety Data

• Hazardous Substances Data: 106119-12-4(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 106-54-7 p-Chlorothiophenol 
• 14204-31-0 2-(4-chlorophenylthio)isoindoline-1,3-dione 
• 106119-09-9 C₁₇H₁₇N₃O₄S 
• 106119-07-7 C₁₇H₁₇ClN₂O₂S 
• 106119-08-8 C₁₈H₂₀N₂O₂S 
• 111680-12-7 N,N'-bis(p-chlorophenylthio)-N,N'-bis(ethoxycarbonyl)hydrazine 
• 15199-28-7 3-(4-chloro-phenylsulfanyl)-5,5-dimethyl-imidazolidine-2,4-dione 

Downstream Products

• 22771-99-9 4-((4-chlorophenyl)sulfonyl)morpholine 

Relevant articles and documents

Iodine/Manganese Dual Catalysis for Oxidative Dehydrogenation Coupling of Amines with Thiols

A novel dual catalytic system of iodine and manganese is used for the first time for oxidative dehydrogenation coupling of amines with thiols during aerobic oxidation. Sulfenamides are synthesized via this approach with moderate to high efficiencies. The mechanistic studies indicate that activated MnO2 is an electron transfer bridge for assisting iodine in completing the catalytic cycle.

N3-(ARYLTHIO-, ARALKYLTHIO- AND ALKYLTHIO)-5,5-DIMETHYLHYDANTOINS: SULFENYL GROUP TRANSFER REACTIONS AND THEIR PROPERTIES

Sulfenyl-transfer reactions toward a variety of nucleophiles were successfully carried out using N3-sulfenyl-substituted 5,5-dimethylhydantoins (2a-c).During the course of the synthesis of 2 by the reaction of N1-bromo-5,5-dimethylhydantoin (1c) with disulfides, the sulfenyl groups were found to be at the position of N3 although the bromine was at N1 in the starting monobromohydantoin (1c).Some mechanistic speculations were considered for the formation of 2 from 1c.

REACTION OF ARENESULFINIMIDIC ACID DERIVATIVES WITH THIOPHENOLS

The amides and esters of N-substituted arenesulfinimidic acids are reduced by the action of thiophenols primarily to N-substituted arenesulfenamides, while the thiophenols are oxidized to the corresponding derivatives of the arenesulfinic acids.