106380-62-5

Basic information

• Product Name: 1H-Benzimidazole, 2-cyclohexyl-1-methyl-
• CAS NO: 106380-62-5
• Molecular Formula: C14H18N2
• Molecular Weight: 214.31
• Mol File: 106380-62-5.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 1H-Benzimidazole, 2-cyclohexyl-1-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Benzimidazole, 2-cyclohexyl-1-methyl-(106380-62-5)
• EPA Substance Registry System: 1H-Benzimidazole, 2-cyclohexyl-1-methyl-(106380-62-5)

Safety Data

• Hazardous Substances Data: 106380-62-5(Hazardous Substances Data)

Upstream product

• 100875-35-2 cyclohexanecarboxylic acid-(2-amino-N-methyl-anilide) 
• 4760-34-3 N-methyl-1,2-phenylenediamine 
• 1632-83-3 1-Methylbenzimidazole 
• 110-82-7 cyclohexane 
• 446065-11-8 cyclohexyltrifluoro-λ⁴-borane potassium salt 
• 4441-56-9 cyclohexylboronic acid 
• 98-89-5 Cyclohexanecarboxylic acid 
• 108-85-0 1-bromocyclohexane 
• 3218-02-8 cyclohexylmethylamine 
• 2043-61-0 cyclohexanecarbaldehyde 
• 766-05-2 cyclohexane carbonitrile 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 100723-26-0 cyclohexanecarboxylic acid-(N-methyl-2-nitro-anilide) 
• 612-28-2 2-nitro-N-methylaniline 

Relevant articles and documents

Visible Light-Mediated Direct Decarboxylative C-H Functionalization of Heteroarenes

The direct visible light-mediated C-H alkylation of heteroarenes using aliphatic carboxylic acids is reported. This mild method proceeds at low catalyst loadings (0.5 mol %) and has a high functional group tolerance and a broad substrate scope. Notably, f

A dual biomimetic process for the selective aerobic oxidative coupling of primary amines using pyrogallol as a precatalyst. Isolation of the [5 + 2] cycloaddition redox intermediates

A bioinspired organocatalytic cascade reaction mimicking both purpurogallin biosynthesis and copper amine oxidases (CuAOs) activity is described, at room temperature under ambient air, for the activation of the α-C-H bond of primary amines. The reaction sequence uses low-cost commercially available pyrogallol as a precatalyst which undergoes an in situ oxidative self-processing step, resulting in its conversion into natural purpurogallin, a [5 + 2] cycloaddition redox intermediate. This is further involved in the CuAOs-like transamination mechanism for producing, under single turnover, the active biomimetic organocatalyst which mediates the selective oxidative coupling of primary amines, including the non-activated substrates of CuAOs. Without any metal cocatalyst or additives, the protocol gives access to cross-coupled imines as well as 1,2-disubstituted benzimidazoles. The isolation of not easily accessible [5 + 2] cycloaddition redox intermediates provides direct and clear evidence for the proposed dual biomimetic process.

Visible Light-Promoted Aliphatic C-H Arylation Using Selectfluor as a Hydrogen Atom Transfer Reagent

A mild, practical method for direct arylation of unactivated C(sp3)-H bonds with heteroarenes has been achieved via photochemistry. Selectfluor is used as a hydrogen atom transfer reagent under visible light irradiation. A diverse range of chem