1064703-80-5Relevant articles and documents
Selective O-deallylation of o-allyloxyanisoles
Sanz, Roberto,Martínez, Alberto,Marcos, César,Fa?ańas, Francisco J.
, p. 1957 - 1960 (2008)
o-Allyloxyanisoles are selectively and easily deallylated by treatment with sec- or tert-butyllithium at low temperature. The reaction is proposed to proceed through a tandem intermolecular carbolithiation-β;-elimination process, which can also be considered an SN2′ attack of the organolithium on the allyl ether.