201359-55-9

Basic information

• Product Name: 1-(allyloxy)-2-methoxy-4-methylbenzene
• Synonyms: 1-(allyloxy)-2-methoxy-4-methylbenzene
• CAS NO: 201359-55-9
• Molecular Weight: 178.231
• Mol File: 201359-55-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-(allyloxy)-2-methoxy-4-methylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(allyloxy)-2-methoxy-4-methylbenzene(201359-55-9)
• EPA Substance Registry System: 1-(allyloxy)-2-methoxy-4-methylbenzene(201359-55-9)

Safety Data

• Hazardous Substances Data: 201359-55-9(Hazardous Substances Data)

Upstream product

• 121-33-5 vanillin 
• 93-51-6 2-Methoxy-4-methylphenol 
• 106-95-6 allyl bromide 

Downstream Products

• 93-51-6 2-Methoxy-4-methylphenol 
• 1064703-80-5 C₁₁H₁₃⁽²⁾HO₂ 
• 16766-16-8 (2-methoxy-4-methylphenoxy)acetaldehyde 
• 5653-56-5 2,3-dimethoxy-5-methylbenzoic acid 
• 369362-35-6 2-(2,3-dimethoxy-5-methyl-phenyl)-2-methyl-pent-4-enoic acid methyl ester 
• 369362-37-8 2-(2,3-dimethoxy-5-methyl-phenyl)-2-methyl-4-oxo-pentanal 
• 369362-38-9 4-(2,3-dimethoxy-5-methyl-phenyl)-4-methyl-cyclopent-2-enone 
• 369362-36-7 2-(2,3-dimethoxy-5-methyl-phenyl)-2-methyl-pent-4-enal 
• 96202-91-4 (2,3-dimethoxy-5-methyl-phenyl)-acetic acid methyl ester 
• 369362-34-5 2-(2,3-dimethoxy-5-methyl-phenyl)-propionic acid methyl ester 
• 369362-33-4 (2,3-dimethoxy-5-methyl-phenyl)-acetaldehyde 
• 369362-32-3 1-allyl-2,3-dimethoxy-5-methyl-benzene 
• 783333-03-9 (E)-5-(2-tert-butyldimethylsilyloxy-3-methoxy-5-methylphenyl)pent-2-enyl methyl carbonate 
• 783333-00-6 (E)-ethyl 5-(2-tert-butyldimethylsilyloxy-3-methoxy-5-methylphenyl)pent-2-enoate 

Relevant articles and documents

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Structure-activity relationships in the domain of odorants having marine notes

Continuing our investigations into marine note odorants, we herein describe several new scaffolds. Among them, 2,3-dihydrobenzofuran-2-carbaldehyde is particularly interesting. The results demonstrate that the seven-membered ring with a ketone functional group of the Calone 1951 family can be replaced by a five-membered ring carrying an aldehydefunction. In addition, this work has allowed us to discover the valuable 2-methoxy-4-methylphenyl methyl carbonate (20b), which is very close to vanillin, and 2-methoxy-2,4-dimethyl-1,3-benzodioxole (29d), which belongs to the isoeugenol/dihydroeugenol olfactive family.

Selective O-deallylation of o-allyloxyanisoles

o-Allyloxyanisoles are selectively and easily deallylated by treatment with sec- or tert-butyllithium at low temperature. The reaction is proposed to proceed through a tandem intermolecular carbolithiation-β;-elimination process, which can also be considered an SN2′ attack of the organolithium on the allyl ether.