106536-23-6

Basic information

• Product Name: (E)-1-chloro-4-(3-methylbuta-1,3-dien-1-yl)benzene
• Synonyms: (E)-1-chloro-4-(3-methylbuta-1,3-dien-1-yl)benzene
• CAS NO: 106536-23-6
• Molecular Weight: 178.661
• Mol File: 106536-23-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-1-chloro-4-(3-methylbuta-1,3-dien-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-chloro-4-(3-methylbuta-1,3-dien-1-yl)benzene(106536-23-6)
• EPA Substance Registry System: (E)-1-chloro-4-(3-methylbuta-1,3-dien-1-yl)benzene(106536-23-6)

Safety Data

• Hazardous Substances Data: 106536-23-6(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 1383536-73-9 1-chloro-4-(3-methylbuta-1,2-dien-1-yl)benzene 
• 97142-86-4 1-(4-chlorophenyl)but-2-yn-1-ol 
• 847661-06-7 2-methylprop-2-ene-1-sulfonyl fluoride 
• 513-42-8 3-hydroxy-2-methyl-1-propene 

Downstream Products

• 14276-94-9 (3-methylbutyl)-4-chlorobenzene 

Relevant articles and documents

Gold-catalyzed isomerization of unactivated allenes into 1,3-dienes under ambient conditions

We have developed a gold-catalyzed isomerization of unactivated allenes into 1,3-dienes with nitrosobenzene as an additive. This reaction proceeded almost exclusively at room temperature for highly substituted allenes. The utility of this reaction is manifested by the development of one-pot [4+2]-cycloaddition of allenes and reactive alkenes.

THE ONE-POT PALLADIUM CATALYZED WITTIG REACTION WITH ALLYLIC ALCOHOLS. SCOPE AND LIMITATIONS

Some allylic alcohols react with aldehydes and triphenylphosphine in a one-pot formal Wittig reaction under Pd0 catalysis.The method has been extended to cinnamyl alcohol, 1, 2-methyl-2-propen-1-ol, 7, and 3-buten-2-ol, 11, and to heterocyclic aldehydes.