106696-59-7Relevant articles and documents
Manganese-Catalyzed Ring-Opening Coupling Reactions of Cyclopropanols with Enones
Zhang, Yong-Hui,Zhang, Wen-Wei,Zhang, Ze-Yu,Zhao, Kai,Loh, Teck-Peng
, p. 5101 - 5105 (2019/07/03)
A manganese-catalyzed ring-opening coupling reaction of cyclopropanols with enones for the facile and efficient preparation of 1,6-diketones is described. A wide array of synthetically important 1,6-diketones bearing manifold functional groups are obtained with up to 93% yield. These reactions feature broad substrate scopes, environmentally benign conditions, inexpensive catalyst, and operational simplicity.
Synthesis of Stable 1,2-Diazocines, 4,7-Disubstituted 3,8-Diaryl-1,2-diazacycloocta-2,4,6,8-tetraenes and Their Thermolysis
Yogi, Seiichi,Hokama, Kozo,Ueno, Kazunori,Tsuge, Otohiko
, p. 1087 - 1094 (2007/10/02)
Stable 1,2-diazocines, 3,8-diaryl-4,6-dichloro-1,2-diazacycloocta-2,4,6,8-tetraenes, were prepared via a chlorination-dehydrochlorination sequence starting from readily-available 3,8-diaryl-1,2-diazacycloocta-2,4-dienes.When reacted with metal caroxylates in benzene under reflux, the dichloro-1,2-diazocines were converted into stable 4-acyloxy- and/or 4,7-is(acyloxy)-1,2-diazocines.On the thermolysis in toluene under reflux, all the diazocines gave only pyridine derivatives with extrusion of the corresponding benzonitriles.The thermal behavior of the diazocines are also discussed.