107090-89-1

Basic information

• Product Name: (4R,8R)-8-hydroxy-p-menth-1-en-9-yl p-toluenesulfonate
• Synonyms: (4R,8R)-8-hydroxy-p-menth-1-en-9-yl p-toluenesulfonate
• CAS NO: 107090-89-1
• Molecular Weight: 324.441
• Mol File: 107090-89-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4R,8R)-8-hydroxy-p-menth-1-en-9-yl p-toluenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,8R)-8-hydroxy-p-menth-1-en-9-yl p-toluenesulfonate(107090-89-1)
• EPA Substance Registry System: (4R,8R)-8-hydroxy-p-menth-1-en-9-yl p-toluenesulfonate(107090-89-1)

Safety Data

• Hazardous Substances Data: 107090-89-1(Hazardous Substances Data)

Upstream product

• 56031-82-4 2-(4-methylcyclohex-3-en-1-yl)propane-1,2-diol 
• 98-59-9 p-toluenesulfonyl chloride 
• 37905-03-6 8-hydroxygeranyl acetate 
• 56031-82-4 (4R,8R)-p-menth-1-ene-8,9-diol 
• 94853-00-6 (2Z,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 70238-37-8 (2'Z,6'E)-Essigsaeure-(8'-hydroxy-3',7'-dimethyl-2',6'-octadien-1'-yl)ester 
• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 141-12-8 neryl acetate 
• 106-25-2 Nerol 
• 130487-30-8 (2E,6E)-8-Benzyloxy-2,6-dimethyl-2,6-octadienyl Acetate 
• 10090-80-9 9-acetoxy-8-hydroxy-p-menth-1-ene 
• 52188-74-6 (E,E)-8-acetoxy-1-benzyloxy-3,7-dimethylocta-2,6-diene 
• 36052-53-6 trans,trans-2,6-dimethyl-2,6-octadiene-1,8-diyl diacetate 

Downstream Products

• 98-55-5 terpineol 
• 28098-67-1 (R)-2-methyl-2-((R)-4-methylcyclohex-3-enyl)oxirane 
• 121962-39-8 2-(4-methyl-3-cyclohexen-1-yl)-propanal 

Relevant articles and documents

Superacidic cyclization of ω-hydroxygeraniol diacetate and ω-hydroxygeraniol benzyl ether acetate

Low-temperature superacidic cyclization of (E,E)-3,7-dimethylocta-2,6-diene-1,8-diol (ω-hydroxygeraniol) diacetate and (E,E)-8-acetoxy-1-benzyloxy-3,7-dimethylocta-2,6-diene leads to the same mixtures of two diastereomeric 9-acetoxy-8-hydroxy-p-menth-1-enes epimeric at the C(8) atom.

Chemical Tranformation of Terpenoids. V. Acidic Conversions of 10-Hydroxygeraniol and 10-Hydroxynerol Derivatives Leading to Cyclic Monoterpenoids

Acid treatment of 1-O-acetyl-10-hydroxygeraniol (5a), 1-O-methyl-10-hydroxygeraniol (5b), 1-O-acetyl-10-hydroxynerol (6a), and 1-O-methyl-10-hydroxynerol (6b) was investigated under various conditions.It was found that treatment of 5a and 6a with HCOOH gave menth-1-ene-8,9-diol (7), while treatment of 5a, 5b, 6a, or 6b with BF3-etherate in CH2Cl2 furnished two menthofuran-type compounds (9, 10) and two bicyclooct-2-ene derivatives (17, 24).Both 9 and 10 were successfully converted to menthofuran (16) and 17 was converted to a bicyclooctenone derivative (23) which was a key intermediate for a synthesis of juvabione (27).Keywords - geraniol; nerol; 10-hydroxygeraniol; 10-hydroxynerol; 10-hydroxygeraniol derivative; 10-hydroxynerol derivative; uroterpenol; menthofuran; bicyclooct-2-ene derivative