56031-82-4

Basic information

• Product Name: (4R,8R)-p-menth-1-ene-8,9-diol
• Synonyms: (4R,8R)-p-menth-1-ene-8,9-diol
• CAS NO: 56031-82-4
• Molecular Weight: 170.252
• Mol File: 56031-82-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (4R,8R)-p-menth-1-ene-8,9-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,8R)-p-menth-1-ene-8,9-diol(56031-82-4)
• EPA Substance Registry System: (4R,8R)-p-menth-1-ene-8,9-diol(56031-82-4)

Safety Data

• Hazardous Substances Data: 56031-82-4(Hazardous Substances Data)

Upstream product

• 10090-80-9 9-acetoxy-8-hydroxy-p-menth-1-ene 
• 130487-30-8 (2E,6E)-8-Benzyloxy-2,6-dimethyl-2,6-octadienyl Acetate 
• 106-25-2 Nerol 
• 106113-26-2 (1S,2S,4R,8R)-1,2-dibromo-8-hydroxy-p-menth-9-yl 4'-nitrobenzoate 
• 5989-27-5 D-limonene 
• 56086-28-3 (4R,8R)-8-hydroxy-p-menth-1-en-9-yl 4'-nitrobenzoate 
• 98-55-5 terpineol 
• 28664-18-8 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl 2,2,2-trifluoroacetate 
• 10067-30-8 8,9-diacetoxy-p-menth-1-ene 
• 138-86-3 limonene. 
• 94853-00-6 (2Z,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 37905-02-5 (2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 141-12-8 neryl acetate 

Downstream Products

• 107090-89-1 Toluene-4-sulfonic acid 2-hydroxy-2-(4-methyl-cyclohex-3-enyl)-propyl ester 
• 107090-89-1 (4R,8R)-8-hydroxy-p-menth-1-en-9-yl p-toluenesulfonate 
• 14675-11-7 p-menthane-8,9-diol 
• 98-55-5 terpineol 
• 72257-53-5 (-)-α2-acetyloxy-1,8-cineole 
• 72257-53-5 (+)-α2-acetyloxy-1,8-cineole 
• 18679-55-5 (+/-)-2-oxo-1,8-cineole 
• 18679-48-6 (+/-)-β2-hydroxy-1,8-cineole 
• 72257-53-5 cis-2-acetoxy-1,8-cineole 
• 72257-53-5 (+)-β2-acetyloxy-1,8-cineole 
• 72257-53-5 (-)-β2-acetyloxy-1,8-cineole 
• 72447-56-4 9-Hydroxycineole 
• 18679-48-6 2-endo-hydroxy-1,8-cineole ((1R,6R)-1,3,3-trimethyl-2-oxabicyclo-[2.2.2]octan-6-ol) 
• 72257-53-5 (+/-)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol acetate 

Relevant articles and documents

Traceless Silylation of β-C(sp3)-H Bonds of Alcohols via Perfluorinated Acetals

We report the silylation of primary C-H bonds located β to secondary and tertiary alcohols by exploiting perfluorinated esters as traceless directing groups. The conversion of a secondary or tertiary alcohol to a perfluoroalkyl ester and conversion of the ester to the corresponding silyl acetals by hydrosilylation allows for selective β-C(sp3)-H silylation catalyzed by the combination of [Ir(cod)OMe]2 and Me4Phen (3,4,7,8-tetramethyl-1,10-phenanthroline) to form 6-membered dioxasilinane. Tamao-Fleming oxidation of these dioxasilinane leads to 1,2 diols. The developed sequence was applied to a series of natural products containing hydroxyl groups.

Superacidic cyclization of ω-hydroxygeraniol diacetate and ω-hydroxygeraniol benzyl ether acetate

Low-temperature superacidic cyclization of (E,E)-3,7-dimethylocta-2,6-diene-1,8-diol (ω-hydroxygeraniol) diacetate and (E,E)-8-acetoxy-1-benzyloxy-3,7-dimethylocta-2,6-diene leads to the same mixtures of two diastereomeric 9-acetoxy-8-hydroxy-p-menth-1-enes epimeric at the C(8) atom.

Halogenated Terpenoids. XXII. Uroterpenol. The C8 Stereochemistry

The two diastereoisomeric p-menth-1-ene-8,9-diols (uroterpenols) have been separated and crystallized.A crystallographic analysis of a dibromo derivative enables relative and absolute configurations to be assigned throughout the series.