107126-07-8

Basic information

• Product Name: diethyl 4-methylphenyl(methylthio)methylphosphonate
• Synonyms: diethyl 4-methylphenyl(methylthio)methylphosphonate
• CAS NO: 107126-07-8
• Molecular Weight: 288.348
• Mol File: 107126-07-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: diethyl 4-methylphenyl(methylthio)methylphosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 4-methylphenyl(methylthio)methylphosphonate(107126-07-8)
• EPA Substance Registry System: diethyl 4-methylphenyl(methylthio)methylphosphonate(107126-07-8)

Safety Data

• Hazardous Substances Data: 107126-07-8(Hazardous Substances Data)

Upstream product

• 28975-74-8 diethyl methylthio(chloro)methanephosphonate 
• 108-88-3 toluene 
• 50746-61-7 diethyl (methylsulfinyl)methylphosphonate 
• 28460-01-7 diethyl 1-(methylthio)methylphosphonate 

Relevant articles and documents

REACTION OF PUMMERER REARRANGEMENT INTERMEDIATE WITH AROMATIC COMPOUNDS: A NOVEL SYNTHESIS OF 1-(SUBSTITUTED-ARYL)METHYLTHIOMETHANEPHOSPHONATES

Pummerer reaction intermediate(2) of methylsulfinylmethanephosphonate(1) has been found to react mildly with aromatic compounds in the presence of tin(IV) chloride to afford 1-(substituted-aryl)methylthiomethanephosphonates.

ARYLATION OF α-PHOSPHORYL SULFIDES VIA THEIR PUMMERER REARRANGEMENT INTERMEDIATES GENERATED FROM THE CORRESPONDING SULFOXIDES

Various aryl groups were introduced directly into the α-position of α-phosphoryl sulfides by treating their sulfoxides with trifluoroacetic anhydride and then with tin(IV) chloride in the presence of excess of the aryl compound.