1089690-04-9

Basic information

• Product Name: 2-benzyl-1-benzylidene-2-m-tolylhydrazine
• CAS NO: 1089690-04-9
• Molecular Weight: 300.403
• Mol File: 1089690-04-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-benzyl-1-benzylidene-2-m-tolylhydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-benzyl-1-benzylidene-2-m-tolylhydrazine(1089690-04-9)
• EPA Substance Registry System: 2-benzyl-1-benzylidene-2-m-tolylhydrazine(1089690-04-9)

Safety Data

• Hazardous Substances Data: 1089690-04-9(Hazardous Substances Data)

Upstream product

• 2725-46-4 1-benzyl-2-benzylidene-1-phenylhydrazine 
• 588-64-7 benzaldehyde phenylhydrazone 
• 637-04-7 (3-methylphenyl)hydrazine hydrochloride 
• 100-52-7 benzaldehyde 

Downstream Products

• 24781-11-1 1-benzyl-6-methyl-2-phenyl-1H-benzo[d]imidazole 
• 52159-88-3 1-benzyl-4-methyl-2-phenyl-1H-benzo[d]imidazole 

Relevant articles and documents

Copper-mediated synthesis of substituted 2-aryl-N-benzylbenzimidazoles and 2-arylbenzoxazoles via C-H functionalization/C-N/C-O bond formation

An efficient method for the transformation of N-benzyl bisarylhydrazones and bisaryloxime ethers to functionalized 2-aryl-N-benzylbenzimidazoles and 2-arylbenzoxazoles is described. The protocol involves a copper(II)-mediated cascade C-H functionalization/C-N/C-O bond formation under neutral conditions. Substrates having either electron-donating or -withdrawing substituents undergo the cyclization to afford the target heterocycles at moderate temperature.