109240-68-8

Basic information

• Product Name: 4-benzyloxymethyl-2,2,4-trimethyl-1,3-dioxolane
• Synonyms: 4-benzyloxymethyl-2,2,4-trimethyl-1,3-dioxolane
• CAS NO: 109240-68-8
• Molecular Weight: 236.311
• Mol File: 109240-68-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-benzyloxymethyl-2,2,4-trimethyl-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-benzyloxymethyl-2,2,4-trimethyl-1,3-dioxolane(109240-68-8)
• EPA Substance Registry System: 4-benzyloxymethyl-2,2,4-trimethyl-1,3-dioxolane(109240-68-8)

Safety Data

• Hazardous Substances Data: 109240-68-8(Hazardous Substances Data)

Upstream product

• 109240-65-5 (R)-[2-(benzyloxymethyl)oxiran-2-yl]methanol 
• 109240-66-6 2?(benzyloxymethyl)prop?2?en?1?ol 
• 100-39-0 benzyl bromide 
• 86940-97-8 (R)-(+)-2,2,4-trimethyl-4-(hydroxymethyl)-1,3-dioxolane 
• 109240-67-7 (S)-1-benzyloxy-2-methylpropane-2,3-diol 
• 77-76-9 2,2-dimethoxy-propane 
• 126971-16-2 methyl 2,2,4-trimethyl-1,3-dioxolane-4-carboxylate 

Downstream Products

• 365513-15-1 (3-benzyloxy-2-hydroxy-2-methyl)propyl methanesulfonate 
• 116216-91-2 (S)-2-benzyloxymethyl-2-methyloxirane 
• 86940-97-8 (R)-(+)-2,2,4-trimethyl-4-(hydroxymethyl)-1,3-dioxolane 
• 109240-67-7 (S)-1-benzyloxy-2-methylpropane-2,3-diol 

Relevant articles and documents

An alternative approach to (S)- and (R)-2-methylglycidol O-benzyl ether derivatives

This report describes the gram scale synthesis of (S)- and (R)-2,2,4-trimethyl-4-(hydroxymethyl)-1,3-dioxolanes using the Sharpless asymmetric dihydroxylation (AD) of the Weinreb amide of 2-methyl-2-propenoic acid. The 2-methylglycerol acetonides resultan