109493-07-4

Basic information

• Product Name: (E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one
• Synonyms: (E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one
• CAS NO: 109493-07-4
• Molecular Weight: 374.596
• Mol File: 109493-07-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one(109493-07-4)
• EPA Substance Registry System: (E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one(109493-07-4)

Safety Data

• Hazardous Substances Data: 109493-07-4(Hazardous Substances Data)

Upstream product

• 109492-81-1 6-(4-methoxyphenyl)-6-methyl-9-trimethylsilylundeca-1,8-dien-5-one 
• 104-01-8 4-Methoxyphenylacetic acid 
• 36551-06-1 3-(tetrahydropyran-2-yloxy)-1-trimethylsilylprop-1-yne 
• 942-54-1 2-(4-methoxyphenyl)propanoic acid 
• 23786-14-3 4-methoxy-phenyl acetic acid methyl ester 
• 119393-05-4 α-methyl 4-methoxyphenylacetyl chloride 
• 50415-73-1 methyl 2-(4-methoxyphenyl)propionate 
• 109492-89-9 3-trimethylsilylpent-2-en-1-ol 
• 109492-90-2 1-bromo-3-trimethylsilylpent-2-ene 
• 109492-88-8 1-(tetrahydropyran-2-yloxy)-3-trimethylsilylpent-2-ene 
• 109492-79-7 2-(4-methoxyphenyl)hept-6-en-3-one 

Downstream Products

• 109492-83-3 6-(4-methoxyphenyl)-6-methylundec-10-ene-3,7-dione 
• 109492-85-5 10,11-epoxy-6-(4-methoxyphenyl)-6-methylundecan-3,7-dione 

Relevant articles and documents

Studies on the Synthesis of Aphidicolin. Preparation of Aromatic Precursors for Spirocyclic Dienone Formation

Novel syntheses of the alkanediones (12; R=Me, or CH2Ph) and the corresponding epoxides (13) are described.Attempts to cyclise these compounds to the spirocyclic dienone (4) were unsuccessful.Model studies on the phenolic keto cyano toluene-p-sulphonate (24) showed that the cyclopropane(25) was formed preferentially.A variety of related model compounds (29), (31), (32), and (37) were prepared and studied, but none could be cyclised to spirocyclic dienones.