112078-00-9

Basic information

• Product Name: N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide
• Synonyms: N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide
• CAS NO: 112078-00-9
• Molecular Weight: 848.653
• Mol File: 112078-00-9.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide(112078-00-9)
• EPA Substance Registry System: N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide(112078-00-9)

Safety Data

• Hazardous Substances Data: 112078-00-9(Hazardous Substances Data)

Upstream product

• 24544-04-5 2,6-diisopropylbenzenamine 
• 128-69-8 perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride 
• 4048-33-3 6-amino-1-hexanol 
• 156028-26-1 1,6,7,12-tetrachloro-perylene-3,4,9,10-tetracarboxylic acid dianhydride 

Downstream Products

• 1189541-10-3 C₇₆H₅₈N₂O₁₂ 
• 112078-03-2 N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetra(4-bromophenoxy)perylene-3,4:9,10-tetracarboxylic acid diimide 
• 675609-94-6 1,6,7,12-tetrakis(4-iodophenoxy)-N,N'-(2,6-diisopropylphenyl)perylenetetracarboxy-3,4:9,10-diimide 
• 112100-07-9 bis(2,6-diisopropylphenyl)-5,6,12,13-tetraphenoxyanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H, 9H)-tetraone 
• 82953-57-9 Lumogen F Orange 240 

Relevant articles and documents

Facile synthesis of pure 1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxy bisanhydride and bisimide

A robust and scalable procedure to obtain pure 1,6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxy bisanhydride, a highly valuable synthon, has been developed via synthesis of a novel intermediate compound 1,6,7,12-perylene-3,4,9,10-tetracarboxy tetrabutylester.

Synthesis and characterization of fluorescent dyes and their applications for the enhancement of growth rate of Chlorella vulgaris

Spectral conversion of solar radiation from green to red light can enhance the photosynthesis efficiency of microalgae. This can lead to significant increase in microalgal growth. Four perylene-based fluorescent dyes were synthesized to convert wavelengths of light from green (500–570 nm) to orange-red (580–650 nm). These dyes were applied in microalgal cultivation system using two methodologies: (1) light-converting layer, and (2) light-converting medium. The dyes were dissolved in either ethanol or water to form light-converting layers between microalgae culture and the light source. Under converted light in both set-ups, Chlorella vulgaris cultures showed maximum increase in lipid productivity by 13.00% and 17.15%, and biomass productivity by 31.65% and 37.66% compared to the control. Overall, the cultivation results confirmed beneficial effects of modified light on microalgae cultures both on their lipid and biomass productivities. Note that both growth parameters achieved higher performance in the light-converting medium thereby the effectiveness of the cultivation method was validated.

A compound. Colorant and colored resin composition

The present invention addresses the problem of providing a colored resin composition capable of forming a color filter excellent in light resistance, a colorant contained in the colored resin composition, and a benzoperylene compound useful as a dye. A co

PERYLENE BISIMIDE BASED COMPOUNDS AND DYES COMPRISING THE SAME

The present invention relates to a perylene bisimide-based compound represented by the following chemical formula 1 capable of providing dye having less fluorescence reduction at a high temperature while having excellent solubility in an organic solvent,

Perylenetetracarboxy-3,4:9,10-diimide derivatives with large two-photon absorption activity

Three new perylenetetracarboxy-3,4:9,10-diimides, bearing 2,6-diisopropylphenyl groups at the imide positions and 4-(R-ethynyl)phenoxy moieties (R = 4,7-di(2-thienyl)benzo[c][1,2,5]thiadiazole (P2), pyrene (P3) or pyrene-CH2OCH2 (P4)) at the four bay positions, were prepared, along with the known related derivative (R = phenyl (P1)), and well characterized. They have large two-photon absorption (TPA) cross-sections (σ2), as determined by the Z-scan technique, the highest values being reached with P2 which bears a planar π-delocalized donor moiety. P3 is characterized by higher σ2 values than both P1, as expected for the higher π-conjugation of the donor pyrene moiety with respect to phenyl, and P4, due to the presence of the flexible and non-conjugated CH2OCH2 bridge between the pyrene and the ethynyl fragment in the latter compound. The molecular geometry of P1-P4 has been optimized by DFT modeling, showing that in P2 and P3 the bay substituents are stacked due to the π-π interactions of both pyrene and thiophene groups. The LUMO of P1-P4 lies at the same energy and is essentially delocalized on the perylene core whereas the HOMO and HOMO?1 of both P2 and P3 are degenerate and do not show contribution from the perylene core contrarily to that of P1 and P4. The HOMO-LUMO gap is therefore essentially influenced by the HOMO which reflects the electronic charge delocalization on the bay substituents, the lower gaps being observed for P2 and P3, which are characterized by the best TPA properties.