112313-19-6

Basic information

• Product Name: (1R,2S,6R,7S)-4-(2,6-Dimethyl-phenyl)-4-aza-tricyclo[5.2.2.0^2,6]undec-10-ene-3,5,8-trione
• CAS NO: 112313-19-6
• Molecular Weight: 295.338
• Mol File: 112313-19-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S,6R,7S)-4-(2,6-Dimethyl-phenyl)-4-aza-tricyclo[5.2.2.0^2,6]undec-10-ene-3,5,8-trione(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,6R,7S)-4-(2,6-Dimethyl-phenyl)-4-aza-tricyclo[5.2.2.0^2,6]undec-10-ene-3,5,8-trione(112313-19-6)
• EPA Substance Registry System: (1R,2S,6R,7S)-4-(2,6-Dimethyl-phenyl)-4-aza-tricyclo[5.2.2.0^2,6]undec-10-ene-3,5,8-trione(112313-19-6)

Safety Data

• Hazardous Substances Data: 112313-19-6(Hazardous Substances Data)

Upstream product

• 87-62-7 2,6-dimethylaniline 
• 1206-49-1 N-(2,6-dimethylphenyl)maleimide 
• 108-95-2 phenol 

Relevant articles and documents

Thermal Cycloaddition of N-Arylmaleimides to Phenols: the Convenient Synthesis of Bicyclooct-2-en-5-one and Tricyclo2,8>octan-2-one Derivatives from Phenols

Monohydric phenols undergo 2,5-thermal cycloaddition of N-substituted maleimides to give bicyclooct-2-en-5-ones.Homopolymers of the maleimides are also concurrently formed, except in the case of N-(2,6-dimethylphenyl)maleimide: this is the preferred addend and gave a 63percent yield of the 2,5-adduct as a mixture of exo and endo isomers.U.v. irradiation in acetone of the diester (16) derived from the endo adduct of phenol and N-phenylmaleimide gave the tricyclo2,8>octan-3-one (17) in quantitative yield.