114049-86-4

Basic information

• Product Name: N-(4'-Chloro-biphenyl-2-ylmethyl)-3,4-dimethoxy-benzamide
• CAS NO: 114049-86-4
• Molecular Weight: 381.859
• Mol File: 114049-86-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4'-Chloro-biphenyl-2-ylmethyl)-3,4-dimethoxy-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4'-Chloro-biphenyl-2-ylmethyl)-3,4-dimethoxy-benzamide(114049-86-4)
• EPA Substance Registry System: N-(4'-Chloro-biphenyl-2-ylmethyl)-3,4-dimethoxy-benzamide(114049-86-4)

Safety Data

• Hazardous Substances Data: 114049-86-4(Hazardous Substances Data)

Upstream product

• 153850-81-8 [1-(4'-Chloro-biphenyl-2-yl)-meth-(E)-ylidene]-isopropyl-amine 
• 153850-85-2 4'-Chloro-biphenyl-2-carbaldehyde oxime 
• 153850-83-0 4'-chlorobiphenyl-2-carboxaldehyde 
• 135-02-4 ortho-anisaldehyde 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 13033-50-6 N-(2-methoxybenzylidene)isopropylamine 
• 3535-37-3 3,4-dimethoxybenzoic acid chloride 

Downstream Products

• 114069-75-9 N-(4'-Chloro-biphenyl-2-ylmethyl)-3,4-dimethoxy-benzimidoyl chloride 
• 114049-95-5 C₂₂H₁₈ClNO₂ 

Relevant articles and documents

Reactions of Diene-conjugated 1,3-Dipolar Intermediates: A Versatile and Efficient Route to Dibenzazepines via Benzonitrile o-Arylbenzyl Ylides

Diene-conjugated nitrile ylides of the type 1 in which both the α,β- and the γ,δ-double bonds are aromatic and where R is either hydroger or a para substitutent, cyclise to give dibenzazepines21 (Scheme 2) in high yield.This is in contrast to the analogous diazo system 2 in which cyclisation do not occur.The presence of an ortho methyl group in the ring under attack (1j, Scheme 3) prevents cyclisation via its steric limitations of conjugation in the transition state.