13033-50-6

Basic information

• Product Name: N-(2-methoxybenzylidene)isopropylamine
• Synonyms: N-(2-methoxybenzylidene)isopropylamine
• CAS NO: 13033-50-6
• Molecular Weight: 177.246
• Mol File: 13033-50-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: N-(2-methoxybenzylidene)isopropylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-methoxybenzylidene)isopropylamine(13033-50-6)
• EPA Substance Registry System: N-(2-methoxybenzylidene)isopropylamine(13033-50-6)

Safety Data

• Hazardous Substances Data: 13033-50-6(Hazardous Substances Data)

Upstream product

• 75-31-0 isopropylamine 
• 135-02-4 ortho-anisaldehyde 

Downstream Products

• 124915-16-8 C₁₆H₁₈O₂Se₂ 
• 756474-36-9 N-(2-methoxybenzyl)-iso-propylamine 
• 1203-68-5 2-Phenylbenzaldehyde 
• 169618-84-2 [1,1’:3’,1’’-terphenyl]-2’-carbaldehyde 
• 142598-69-4 2-(naphthalene-1-yl)benzaldehyde 
• 223575-47-1 2-(naphthalen-2’-yl)benzaldehyde 
• 216443-17-3 3’-methyl-[1,1’]-biphenyl-2-carbaldehyde 
• 16191-28-9 2-(4-methylphenyl)benzaldehyde 
• 16064-04-3 2-(4-methoxyphenyl)benzaldehyde 
• 114049-86-4 N-(4'-Chloro-biphenyl-2-ylmethyl)-3,4-dimethoxy-benzamide 
• 114069-75-9 N-(4'-Chloro-biphenyl-2-ylmethyl)-3,4-dimethoxy-benzimidoyl chloride 

Relevant articles and documents

Bismuth-catalyzed synthesis of polycyclic aromatic hydrocarbons (PAHs) with a phenanthrene backbone via cyclization and aromatization of 2-(2-arylphenyl)vinyl ethers

The reaction of 2-(2-arylphenyl)vinyl ethers in the presence of a catalytic amount of bismuth(III) triflate gave substituted phenanthrenes in excellent yields under mild reaction conditions. The reaction was also applied to the construction of other polycyclic aromatic hydrocarbons (PAHs), such as chrysene, helicene, and pyrene having a phenanthrene backbone, via regioselective cyclization. This method has the advantages of easy availability of the cyclization precursors, operational simplicity, and high reaction efficiency.

Catalytic Asymmetric Synthesis of N-Chiral Amine Oxides

Direct asymmetric synthesis of N-chiral amine oxides was accomplished (up to 91:9 e.r.) by means of a bimetallic titanium catalyst. A hydroxy group situated at the γ-position of the N stereocenter enables the desired N-oxidation through dynamic kinetic resolution of the trivalent amine substrates. The method was further extended to the kinetic resolution of racemic γ-amino alcohols with a preexisting stereocenter, giving an important class of enantioenriched (up to 99.9:0.1 e.r.) building blocks that are otherwise difficult to synthesize.