114218-29-0

Basic information

• Product Name: 1L-1-O-allyl-2,3,4,5,6-penta-O-benzyl-myo-inositol
• Synonyms: 1L-1-O-allyl-2,3,4,5,6-penta-O-benzyl-myo-inositol
• CAS NO: 114218-29-0
• Molecular Weight: 670.846
• Mol File: 114218-29-0.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 1L-1-O-allyl-2,3,4,5,6-penta-O-benzyl-myo-inositol(CAS DataBase Reference)
• NIST Chemistry Reference: 1L-1-O-allyl-2,3,4,5,6-penta-O-benzyl-myo-inositol(114218-29-0)
• EPA Substance Registry System: 1L-1-O-allyl-2,3,4,5,6-penta-O-benzyl-myo-inositol(114218-29-0)

Safety Data

• Hazardous Substances Data: 114218-29-0(Hazardous Substances Data)

Upstream product

• 26276-99-3 rac-1,4,5,6-tetra-O-benzyl-myo-inositol 
• 100-39-0 benzyl bromide 
• 114218-18-7 (-)-ω-camphanate of 1D-1,2,4-tri-O-benzyl-5,6-O-isopropylidene-myo-inositol 
• 111446-91-4 (+/-)-1,2,4-tri-O-benzyl-5,6-O-isopropylidene-myo-inositol 
• 114218-19-8 1D-3-O-allyl-1,2,4-tri-O-benzyl-5,6-O-isopropylidene-myo-inositol 
• 18311-26-7 methyl 6-O-trityl-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 85716-43-4 methyl 6-deoxy-6-iodo-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 85716-44-5 methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside 
• 133218-74-3 4,5,6-tri-O-benzyl-1,2-anhydro-myo-inositol 
• 102997-58-0 (1R,2R,3S)-tris(phenylmethoxy)-6S-hydroxy-cyclohex-4-ene 
• 85798-11-4 (4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 2595-06-4 methyl 2,3,4-tri-O-benzyl-6-O-trityl-α-D-glucopyranoside 

Downstream Products

• 158340-85-3 1,2,3,4,5-Penta-O-benzyl-D-chiro-inositol 
• 852066-09-2 Octadecanoic acid (R)-1-(6-amino-hexanoyloxymethyl)-2-[hydroxy-((1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentahydroxy-cyclohexyloxy)-phosphoryloxy]-ethyl ester 
• 6195-45-5 (+)-2,3,4,5,6-pentakis-O-benzyl myo-inositol 
• 26277-05-4 1,2,4,5,6-penta-O-benzyl-sn-myo-inositol 
• 111828-82-1 D-1-O-[(1S)-(-)-camphanoyl]-2,3,4,5,6-penta-O-benzyl-myo-inositol 
• 111901-81-6 L-1-O-[(1S)-(-)-camphanoyl]-2,3,4,5,6-penta-O-benzyl-myo-inositol 
• 108235-14-9 D,L-2,3,4,5,6-penta-O-benzyl-myo-inositol 1-(methanesulfonate) 
• 134275-56-2 myo-inositol 1-(-3,4-di-palmitoyloxybutyl)-sulfonate 
• 134275-56-2 myo-inositol 1-(-3,4-di-palmitoyloxybutyl)-sulfonate 
• 134275-53-9 2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-ethanesulfonic acid (1S,2R,3R,4S,5S,6R)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl ester 
• 134275-53-9 2-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-ethanesulfonic acid (1S,2S,3R,4S,5S,6S)-2,3,4,5,6-pentakis-benzyloxy-cyclohexyl ester 

Relevant articles and documents

1D- and 1L-1,2:4,5-di-O-cyclohexylidene-3-O-allyl-myo-inositols: Complementary versatile new starting materials for syntheses in the 1D-myo- inositol series

The preparation and proof of absolute configuration as 1D- and 1L- respectively are presented for (-)and (+)-1,2:4,5-di-O-cyclohexylidene-3-O- allyl-myo-inositol, two versatile complementary materials equally suitable for syntheses in the 1D-myo-inositol

Syntheses of penta-O-benzyl-myo-inositols, O-β-L-arabinosyl-(1 → 2)sn-myo-inositol, O-α-D-galactosyl-(1 → 3)-sn-myo-inositol, and O-α-D-galactosyl-(1 → 6)-O-α-D-galactosyl-(1 → 3)-sn-myo-inositol

Two-step conversions of myo-inositol into (±)-2,3,4,5,6- and 1,3,4,5,6-penta-O-benzyl-myo-inositols are described. Starting from these monohydroxy derivatives of myo-inositol, O-β-L-arabinopyranosyl-(1→2)-sn-myo-inositol from Japanese green tea, Camellia sinensis, and O-α-D-galactopyranosyl-(1→3)-sn-myo-inositol (galactinol) as well as its homolog, O-α-D-galactopyranosyl-(1→6(II))-galactinol, were synthesized by way of the in situ activating glycosylation procedure.

The absolute configuration of (+)-1,2,4,5,6-penta-O-benzyl-myo-inositol

The absolute configuration of (+)-1,2,4,5,6-penta-O-benzyl-myo-inositol is correlated with 1D-1,4,5,6-tetra-O-benzyl-myo-inositol and thus confirmed as 1D-1,2,4,5,6-penta-O-benzyl-myo-inositol.