114218-18-7

Basic information

• Product Name: (1R,4S)-4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (3aS,4S,5S,6S,7R,7aS)-4,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-yl ester
• CAS NO: 114218-18-7
• Molecular Weight: 670.8
• Mol File: 114218-18-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,4S)-4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (3aS,4S,5S,6S,7R,7aS)-4,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4S)-4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (3aS,4S,5S,6S,7R,7aS)-4,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-yl ester(114218-18-7)
• EPA Substance Registry System: (1R,4S)-4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (3aS,4S,5S,6S,7R,7aS)-4,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-yl ester(114218-18-7)

Safety Data

• Hazardous Substances Data: 114218-18-7(Hazardous Substances Data)

Upstream product

• 114218-18-7 (1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (3aR,4R,5R,6R,7S,7aR)-4,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-yl ester 
• 111446-91-4 (+/-)-1,2,4-tri-O-benzyl-5,6-O-isopropylidene-myo-inositol 
• 125474-19-3 1D-2,3,6-Tri-O-benzyl-4,5-O-isopropylidene-myo-inositol 
• 39637-74-6 (-)-camphanic acid chloride 
• 39637-74-6 (1S)-(-)-camphanic chloride 
• 111446-91-4 (+/-)-1,6-O-isopropylidene-2,4,5-tri-O-benzyl-myo-inositol 

Downstream Products

• 104873-76-9 2,3,6-tris-O-(phenylmethyl)-D-myo-inositol 
• 109522-11-4 Phosphorous acid bis-(2-cyano-ethyl) ester (1S,2R,3R,4S,5S,6S)-2,3,6-tris-benzyloxy-4,5-bis-[bis-(2-cyano-ethoxy)-phosphanyloxy]-cyclohexyl ester 
• 141040-51-9 1D-2,5,6-Tri-O-benzyl-myo-inositol 1,3,4-tris 
• 114218-18-7 (1R,4S)-4,7,7-Trimethyl-3-oxo-2-oxa-bicyclo[2.2.1]heptane-1-carboxylic acid (3aS,4S,5S,6S,7R,7aS)-4,6,7-tris-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-yl ester 
• 141040-35-9 1D-1,2,3,4-Tetra-O-benzyl-myo-inositol 
• 141040-34-8 1D-1,2,3,4-Tetra-O-benzyl-5,6-O-isopropylidene-myo-inositol 
• 114218-19-8 1D-3-O-allyl-1,2,4-tri-O-benzyl-5,6-O-isopropylidene-myo-inositol 
• 80971-00-2 1D-1,2,4-tri-O-benzyl-5,6-O-isopropylidene-3-O-methyl-myo-inositol 
• 114218-16-5 1L-(-)-1-O-allyl-2,3,6-tri-O-benzyl-myo-inositol 
• 80971-02-4 1D-1,2,4-tri-O-benzyl-3-O-methyl-myo-inositol 
• 114297-91-5 1D-(-)-1,2,4-tri-O-benzyl-myo-inositol 
• 114218-30-3 1D-3-O-(prop-1'-enyl)-1,2,4,5,6-penta-O-benzyl-myo-inositol 
• 114218-29-0 1L-1-O-allyl-2,3,4,5,6-penta-O-benzyl-myo-inositol 
• 26277-05-4 1,2,4,5,6-penta-O-benzyl-sn-myo-inositol 

Relevant articles and documents

The preparation, resolution, and phosphorylation of some benzyl ethers of myo-inositol: Intermediates for the synthesis of myo-inositol phosphates of the phosphatidylinositol cycle

The syntheses of the following chiral compounds are described: 1D-2,3,6-tri-, 1D-2,4,5-tri, 1D-2,5,6-tri-, 1D-1,2,3,4-tetra, 1D-1,2,3,6-tetra-, 1D-1,2,4,5-tetra-, and 1D-2,3,5,6-tetra-0-benzyl-myo-inositol; and 1D-2,5,6-tri-0-benzyl-1-0-p-methoxybenyl- an

The Allyl Group for Protection in Carbohydrate Chemistry. Part 20. Synthesis of 1L-1-O-Methyl-myo-inositol by Resolution of (+/-)-1,2,4-Tri-O-benzyl-myo-inositol

Racemic 1,2,4-tri-O-benzyl-myo-inositol was prepared by two new routes from (+/-)-1,4-di-O-benzyl-5,6-O-isopropylidine-myo-inositol, one route involving the crystalline intermediate (+/-)-1-O-allyl-3,6-di-O-benzyl-4,5-O-isopropylidine-myo-inositol.Oxidati