118362-12-2

Basic information

• Product Name: S-Methyl-S-(4-methoxycarbonylmethyl-phenyl)-N-p-tolylsulfonyl-sulfilimin
• CAS NO: 118362-12-2
• Molecular Weight: 365.474
• Mol File: 118362-12-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: S-Methyl-S-(4-methoxycarbonylmethyl-phenyl)-N-p-tolylsulfonyl-sulfilimin(CAS DataBase Reference)
• NIST Chemistry Reference: S-Methyl-S-(4-methoxycarbonylmethyl-phenyl)-N-p-tolylsulfonyl-sulfilimin(118362-12-2)
• EPA Substance Registry System: S-Methyl-S-(4-methoxycarbonylmethyl-phenyl)-N-p-tolylsulfonyl-sulfilimin(118362-12-2)

Safety Data

• Hazardous Substances Data: 118362-12-2(Hazardous Substances Data)

Upstream product

• 16188-55-9 2-(4-(methylthio)phenyl)acetic acid 
• 1798-06-7 (4-iodophenyl)acetic acid 
• 70290-37-8 (4-methylsulfanyl-phenyl)-acetic acid methyl ester 
• 127-65-1 chloroamine-T 
• 144-86-5 N-chloro-4-methylbenzenesulfonamide 

Relevant articles and documents

Electronic effect, steric hindrance, and anchimeric assistance in oxidation of sulphides. Neighbouring-group participation through Sulphur-oxygen nonbonded interaction

Using a set of sulphides o- and p-XC6H4SMe, the electronic effect, steric hindrance, and anchimeric assistance for electrophilic Cl+ addition by TsNHCI and O-transfer by NalO4 were investigated by a kinetic method. The steric effect and anchimeric assistance of the ortho-substituents were evaluated by comparing the reactivity of ortho- and para-substituted compounds (K = ko/kp). For neighbouringgroup activity the following order was obtained: CH2OH ~ CH2OMe ~ CH2CO2Me CH2CO2H ~ CH2NMe2 CH2C02 - ~ CHO CO2Me ~ CO2H COMe ~ CONH2 C02- Reaction rates show that the anchimeric assistance is governed by an S mellip; 0 or S ... N close contact developed in the transition state between oppositely polarized heteroatoms. Factors controlling neighbouringgroup participation through attractive non-bonded interactions are discussed.