119367-03-2

Basic information

• Product Name: ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-α-D-erythro-hex-2'-enopyranosyl)-2-nitro-2-(ethoxycarbonyl)acetate
• Synonyms: ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-α-D-erythro-hex-2'-enopyranosyl)-2-nitro-2-(ethoxycarbonyl)acetate
• CAS NO: 119367-03-2
• Molecular Weight: 513.544
• Mol File: 119367-03-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-α-D-erythro-hex-2'-enopyranosyl)-2-nitro-2-(ethoxycarbonyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-α-D-erythro-hex-2'-enopyranosyl)-2-nitro-2-(ethoxycarbonyl)acetate(119367-03-2)
• EPA Substance Registry System: ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-α-D-erythro-hex-2'-enopyranosyl)-2-nitro-2-(ethoxycarbonyl)acetate(119367-03-2)

Safety Data

• Hazardous Substances Data: 119367-03-2(Hazardous Substances Data)

Upstream product

• 603-67-8 diethyl nitromalonate 
• 113019-35-5 phenyl 4,6-di-O-benzyl-2,3-dideoxy-α,β-D-erythro-hex-2-enopyranoside 
• 95843-67-7 2,3-Didehydro-2,3-didesoxy-α-D-erythro-(phenyl-hexosid) 
• 62398-09-8 Acetic acid (2R,3S,6R)-2-acetoxymethyl-6-phenoxy-3,6-dihydro-2H-pyran-3-yl ester 
• 100-44-7 benzyl chloride 
• 2873-29-2 D-glucal triacetate 

Downstream Products

• 119366-97-1 ethyl 2-(4',6'-di-O-benzyl-2',3'-dideoxy-α-D-erythro-hex-2'-enopyranosyl)-2-(ethoxycarbonyl)acetate 
• 141407-02-5 Ethyl 2-(2',3'-dideoxy-4',6'-di-O-benzyl-α-D-glucopyranosyl)-2-nitro-2-carboethoxy acetate 

Relevant articles and documents

Palladium(0)-Based Approach to Functionalized C-Glycopyranosides

Phenyl 4,6-di-O-benzyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside 4α or 5β reacts with ethyl malonate, acetylacetone, methyl acetylacetate, ethyl nitroacetate, and ethyl nitromalonate under neutral conditions in the presence of Pd(0) to give regiospecifica