603-67-8 Usage
Description
Diethyl nitromalonate is an organic compound that is primarily utilized as an intermediate in the synthesis of various chemical products. It is known for its thermal decomposition properties, which have been extensively studied.
Uses
1. Used in Chemical Synthesis:
Diethyl nitromalonate is used as a key intermediate for the preparation of 5,5-diethoxycarbonyl-1-pyrroline N-oxide (DECPO), a compound with potential applications in various industries.
2. Used in Research and Development:
The thermal decomposition of diethyl nitromalonate to furoxan has been a subject of study, contributing to the understanding of its properties and potential applications in the field of chemistry and material science.
3. Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, diethyl nitromalonate could potentially be used in the pharmaceutical industry as a building block for the synthesis of various drug molecules, given its role as an intermediate in chemical synthesis.
4. Used in Material Science:
The study of diethyl nitromalonate's thermal decomposition could lead to its application in material science, particularly in the development of new materials with specific properties based on the furoxan derived from its decomposition.
Synthesis Reference(s)
Journal of the American Chemical Society, 77, p. 4391, 1955 DOI: 10.1021/ja01621a060
Check Digit Verification of cas no
The CAS Registry Mumber 603-67-8 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,0 and 3 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 603-67:
(5*6)+(4*0)+(3*3)+(2*6)+(1*7)=58
58 % 10 = 8
So 603-67-8 is a valid CAS Registry Number.
InChI:InChI=1/C7H11NO6/c1-3-13-6(9)5(8(11)12)7(10)14-4-2/h5H,3-4H2,1-2H3
603-67-8Relevant articles and documents
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Lorand,J.P. et al.
, p. 4176 - 4178 (1969)
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The Synthesis and Application of Novel Nitrating And Nitrosating Agents
Hakimelahi, Gholam H.,Sharghi, Hashem,Zarrinmayeh, Hamide,Khalafi-Nezhad, Ali
, p. 906 - 915 (2007/10/02)
Alcohols and phenols are efficiently nitrated with thionyl chloride nitrate or thionyl nitrate, even in the presence of an aromatic moiety.While thionyl chloride nitrate is suitable for nitration of primary OH-groups in carbohydrates, thionyl nitrate is reactive enough to react with secondary OH-groups as well.These reagents permit the highly selective nitration of the 5'-, 2',5'- and 3',5'-OH-groups of ribonucleosides to produce either mono- or diprotected nitro derivatives in high yields.Carbon acids and the enol form of some ketones are efficiently nitrated with trifluoromethanesulfonyl nitrate/potassium tert-butoxide.Lutidine N-oxide(2,6-(CH3)2C5H3N->O) was found to have marked effect on nitration reactions.Similarly, thionyl chloride nitrite and thionyl nitrite exhibit an excellent capacity for nitrosation of the aforementioned substrates
