1196473-94-5

Basic information

• Product Name: 4-(1-Hydroxy-3-(nitromethyl)-1,3-dihydrobenzo[c][1,2]oxaborol-6-yloxy)benzoic acid
• Synonyms: 4-(1-Hydroxy-3-(nitromethyl)-1,3-dihydrobenzo[c][1,2]oxaborol-6-yloxy)benzoic acid
• CAS NO: 1196473-94-5
• Molecular Weight: 329.074
• Mol File: 1196473-94-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(1-Hydroxy-3-(nitromethyl)-1,3-dihydrobenzo[c][1,2]oxaborol-6-yloxy)benzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(1-Hydroxy-3-(nitromethyl)-1,3-dihydrobenzo[c][1,2]oxaborol-6-yloxy)benzoic acid(1196473-94-5)
• EPA Substance Registry System: 4-(1-Hydroxy-3-(nitromethyl)-1,3-dihydrobenzo[c][1,2]oxaborol-6-yloxy)benzoic acid(1196473-94-5)

Safety Data

• Hazardous Substances Data: 1196473-94-5(Hazardous Substances Data)

Upstream product

• 59142-68-6 2-bromo-4-fluorobenzaldehyde 
• 1196474-69-7 ethyl 4-(4-formyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)benzoate 
• 1196474-68-6 ethyl 4-(3-bromo-4-formylphenoxy)benzoate 
• 120-47-8 Ethyl 4-hydroxybenzoate 
• 1196473-95-6 ethyl 4-(1-hydroxy-3-(nitromethyl)-1,3-dihydrobenzo[c][1,2]oxaborol-6-yloxy)benzoate 

Relevant articles and documents

Transition-metal-free, one-pot synthesis of benzoxaboroles from: O -bromobenzaldehydes via visible-light-promoted borylation

A novel and simple one-pot stepwise method to synthesize benzoxaboroles was demonstrated. This step-by-step synthetic method includes photocatalytic boronization with phenothiazine as a photocatalyst and sequential water-induced reduction in the presence of bis(pinacolato)diboron. A series of o-bromobenzaldehydes were well-tolerated under the standard conditions. In addition, this method has been successfully applied in the synthesis of the anti-tuberculosis candidate drug GSK 3036656 and anti-fungal drug tavaborole. This journal is