120104-68-9

Basic information

• Product Name: Acetic acid, [(phenylmethoxy)imino]-, methyl ester
• CAS NO: 120104-68-9
• Molecular Formula: C10H11NO3
• Molecular Weight: 193.202
• Mol File: 120104-68-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Acetic acid, [(phenylmethoxy)imino]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [(phenylmethoxy)imino]-, methyl ester(120104-68-9)
• EPA Substance Registry System: Acetic acid, [(phenylmethoxy)imino]-, methyl ester(120104-68-9)

Safety Data

• Hazardous Substances Data: 120104-68-9(Hazardous Substances Data)

Upstream product

• 109745-70-2 methyl glyoxylate methyl hemi-acetal 
• 2687-43-6 O-benzylhydoxylamine hydrochloride 
• 922-68-9 Methyl glyoxylate 
• 622-33-3 N-benzyloxyamine 

Downstream Products

• 77426-68-7 methyl 2-(benzyloxyamino)-3-methylbutanoate 
• 95205-00-8 methyl 2-(benzyloxyamino)butanoate 
• 95205-01-9 methyl 2-(benzyloxyamino)-4-methylpentanoate 
• 95205-02-0 N-(phenylmethoxy)phenylalanine methyl ester 
• 669070-52-4 2-(phenylmethoxyamino)-4-pentenoic acid methyl ester 
• 1227367-15-8 C₁₅H₂₃NO₃ 
• 181826-43-7 ((1S,5R,7R)-10,10-Dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-oxo-acetaldehyde O-benzyl-oxime 

Relevant articles and documents

Remote stereocontrol in reactions between 4- and 5-alkoxyalk-2- enylstannanes and 1-alkoxycarbonylimines and analogues: Stereoselective approaches to novel α-amino acids

Reactions of the allyltin trichloride 45 generated from (4S)-4-benzyloxypent-2-enyl(tributyl)stannane 1 with imines prepared from glyoxylates proceed with useful levels of 1,5-stereocontrol in favour of (4E)-2,6-anti-2-(alkylamino)-6-benzyloxyhept-4-enoat

One-pot synthesis of α-amino acids based on free radical-mediated carbon-carbon bond formation

The one-pot reaction of 2-hydroxy-2-methoxyacetic acid methyl ester with benzyloxyamine and an alkyl radical provided a convenient method for preparing the protected α-amino acids via a carbon-carbon bond formation by intermolecular carbon radical additio