120331-99-9

Basic information

• Product Name: 9-Borabicyclo[3.3.1]nonane, 9-[(1-phenyl-1-propenyl)oxy]-, (Z)-
• CAS NO: 120331-99-9
• Molecular Formula: C17H23BO
• Molecular Weight: 254.18
• Mol File: 120331-99-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 9-Borabicyclo[3.3.1]nonane, 9-[(1-phenyl-1-propenyl)oxy]-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Borabicyclo[3.3.1]nonane, 9-[(1-phenyl-1-propenyl)oxy]-, (Z)-(120331-99-9)
• EPA Substance Registry System: 9-Borabicyclo[3.3.1]nonane, 9-[(1-phenyl-1-propenyl)oxy]-, (Z)-(120331-99-9)

Safety Data

• Hazardous Substances Data: 120331-99-9(Hazardous Substances Data)

Upstream product

• 21205-91-4 9-borabicyclo[3.3.1]nonane dimer 
• 768-03-6 Phenyl vinyl ketone 

Downstream Products

• 34733-55-6 2,3-dimethyl-1,4-diphenyl-butane-1,4-dione 
• 73893-85-3 (2R*,3S*)-2,3-dimethyl-1,4-diphenylbutane-1,4-dione 
• 6084-17-9 2-chloro-1-phenylpropan-1-one 
• 15982-59-9 2-methyl-1,4-diphenylbutane-1,4-dione 
• 34880-83-6 2,3-diethyl-1,4-diphenyl-1,4-butanedione 

Relevant articles and documents

Selective intermolecular oxidative cross-coupling of enolates

Selective intermolecular oxidative cross-coupling of enolates, which is a bond-forming reaction between carbanion equivalents, remains as an unsolved issue despite its potential utility for the direct synthesis of unsymmetrical 1,4-diones. The main difficulty derives from the unavoidable homo-coupling. Our strategy depends on the selective one-electron oxidation of one enolate to afford an electrophilic carbonyl α-radical species, followed by trapping with another enolate. The present study demonstrates the selective oxovanadium(V)-induced cross-coupling between boron and silyl enolates.