1211323-73-7Relevant articles and documents
Stereoselective synthesis of a monocyclic peloruside A analogue
Wulischleger, Christoph W.,Gertsch, Juerg,Altmann, Karl-Heinz
supporting information; experimental part, p. 1120 - 1123 (2010/06/13)
Chemical Equation Presentation The stereoselective synthesis of the monocyclic peloruside A analogue 4 has been achieved, following a new efficient approach for the introduction of the side chain, involving a late-stage addition of vinyl lithium species 7a to aldehyde 8. Further key steps are a highly diastereoselective allyltitanation reaction and a RCM-based macrocyclization.