1211323-74-8

Basic information

• Product Name: (3S,4R,8S,10S,12S,14S)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-dihydroxy-4,12-dimethoxy-9,9-dimethyl-1-oxacyclotetradecan-2-one
• Synonyms: (3S,4R,8S,10S,12S,14S)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-dihydroxy-4,12-dimethoxy-9,9-dimethyl-1-oxacyclotetradecan-2-one
• CAS NO: 1211323-74-8
• Molecular Weight: 640.858
• Mol File: 1211323-74-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4R,8S,10S,12S,14S)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-dihydroxy-4,12-dimethoxy-9,9-dimethyl-1-oxacyclotetradecan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R,8S,10S,12S,14S)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-dihydroxy-4,12-dimethoxy-9,9-dimethyl-1-oxacyclotetradecan-2-one(1211323-74-8)
• EPA Substance Registry System: (3S,4R,8S,10S,12S,14S)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-dihydroxy-4,12-dimethoxy-9,9-dimethyl-1-oxacyclotetradecan-2-one(1211323-74-8)

Safety Data

• Hazardous Substances Data: 1211323-74-8(Hazardous Substances Data)

Upstream product

• 1211323-73-7 (3S,4R,8S,10S,12S,14S,E)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-dihydroxy-4,12-dimethoxy-9,9-dimethyl-1-oxacyclotetradec-5-en-2-one 
• 4910-62-7 potassium diazodicarboxylate 

Relevant articles and documents

Stereoselective synthesis of a monocyclic peloruside A analogue

Chemical Equation Presentation The stereoselective synthesis of the monocyclic peloruside A analogue 4 has been achieved, following a new efficient approach for the introduction of the side chain, involving a late-stage addition of vinyl lithium species 7a to aldehyde 8. Further key steps are a highly diastereoselective allyltitanation reaction and a RCM-based macrocyclization.